1213-40-7

Basic information

• Product Name: Benzenesulfonothioic acid, S-(4-chlorophenyl) ester
• CAS NO: 1213-40-7
• Molecular Formula: C12H9ClO2S2
• Molecular Weight: 284.787
• Mol File: 1213-40-7.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzenesulfonothioic acid, S-(4-chlorophenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonothioic acid, S-(4-chlorophenyl) ester(1213-40-7)
• EPA Substance Registry System: Benzenesulfonothioic acid, S-(4-chlorophenyl) ester(1213-40-7)

Safety Data

• Hazardous Substances Data: 1213-40-7(Hazardous Substances Data)

Upstream product

• 16599-39-6 benzenethiosulfonic acid ; potassium-salt 
• 933-01-7 4-chloro-benzenesulfenyl chloride 
• 33965-85-4 1-(4-chlorophenyl)-2-phenyldisulfane 
• 873-55-2 sodium benzenesulfonate 
• 106-54-7 p-Chlorothiophenol 
• 599-71-3 piloty's acid 
• 98-09-9 benzenesulfonyl chloride 
• 532-32-1 sodium benzoate 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 1887-29-2 sodium phenylthiosulfonate 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 80-17-1 benzenesufonyl hydrazide 
• 42839-20-3 1-((4-chlorophenyl)thio)pyrrolidine-2,5-dione 
• 34220-01-4 di-(4-chlorophenyl)iodonium chloride 

Downstream Products

• 1616956-02-5 (4-chlorophenyl)(cyclooctyl)sulfane 
• 16495-77-5 [(4-chlorophenyl)thio]pentafluorobenzene 
• 29411-04-9 S-(4-chlorophenyl) methylcarbamothioate 
• 7304-69-0 4-chlorophenyl-S-(N,N-dimethylthiocarbamate) 
• 121027-12-1 (4-chlorophenyl)(3-phenylpropyl)sulfane 
• 306278-24-0 3-((4-chlorophenyl)thio)-2-phenylimidazo[1,2-α]pyridine 
• 111698-34-1 (+/-)_S-isopropyl phenylsulfinate 
• 29107-85-5 ethyl 4-((4-chlorophenyl)thio)butanoate 
• 1309446-60-3 ethyl 4-(3-((4-chlorophenyl)thio)-5-(trimethylsilyl)thiophen-2-yl)benzoate 
• 1309446-59-0 3-((4-chlorophenyl)thio)-5-(trimethylsilyl)thiophene-2-carbaldehyde 
• 1309446-72-7 4-(4-chlorophenyl)-3-((4-chlorophenyl)thio)pyridine 

Relevant articles and documents

Visible-Light-Induced Radical Cascade Reaction of 1-Allyl-2-ethynylbenzoimidazoles with Thiosulfonates to Assemble Thiosulfonylated Pyrrolo[1,2-a]benzimidazoles

A visible-light-induced radical domino reaction of 1-allyl-2-ethynylbenzoimidazoles with thiosulfonates was developed, which generated the thiosulfonylated pyrrolo[1,2-a]benzimidazoles in moderate to good yields. This reaction proceeded under transition-metal-free conditions with good functional group tolerance and high regioselectivity. The possible pathway involved thiosulfonates were activated through the energy transfer route promoted by photocatalysis.

The organocatalytic synthesis of perfluorophenylsulfides: Via the thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates

The organic superbase t-Bu-P4-catalyzed direct thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates was developed. Yields of perfluorophenylsulfides of up to 97% under catalysis of 5 mol% t-Bu-P4 were achieved. This method was shown to provide an efficient way to construct the perfluorophenyl-sulfur bond under mild metal-free reaction conditions. This journal is

Visible-light-promoted synthesis of secondary and tertiary thiocarbamates from thiosulfonates andN-substituted formamides

A general visible-light-promoted metal-free synthesis of secondary and tertiary thiocarbamates starting from thiosulfonates andN-substituted formamides is developed. By employing rhodamine B as a photocatalyst andtert-butyl hydroperoxide (TBHP) as an oxidant, a wide scope of thiocarbamates can be obtained through direct thiolation of acyl C-H bonds under irradiation of blue light at room temperature for 12 h.