122603-34-3

Basic information

• Product Name: Benzene, [(1Z)-2-methyl-1,5-hexadienyl]-
• CAS NO: 122603-34-3
• Molecular Formula: C13H16
• Molecular Weight: 172.27
• Mol File: 122603-34-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, [(1Z)-2-methyl-1,5-hexadienyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1Z)-2-methyl-1,5-hexadienyl]-(122603-34-3)
• EPA Substance Registry System: Benzene, [(1Z)-2-methyl-1,5-hexadienyl]-(122603-34-3)

Safety Data

• Hazardous Substances Data: 122603-34-3(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 2327-99-3 1-phenylpropadiene 
• 122603-34-3 (E)-(2-methylhexa-1,5-dien-1-yl)benzene 
• 73222-64-7 (1-Isopropenyl-but-3-enyl)-benzene 
• 1204403-33-7 isopropyl 2-methyl-1-phenylallyl carbonate 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 103729-80-2 2-methyl-1-phenylprop-2-en-1-ol 
• 1504-55-8 (E)-3-phenyl-2-methyl-2-propenol 
• 65693-16-5 (2E)-2-methyl-3-phenylallyl acetate 
• 762-72-1 allyl-trimethyl-silane 

Downstream Products

• 73222-64-7 (1-Isopropenyl-but-3-enyl)-benzene 

Relevant articles and documents

Triflimide-catalyzed allyl-allyl cross-coupling: A metal-free allylic alkylation

A highly efficient metal-free intermolecular C(sp3)-C(sp3) allyl-allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.

Palladium(0) versus nickel(0) catalysis in selective functional- grouptolerant sp3-sp3 carbon-carbon bond formations

We have uncovered Pd°-catalyzed intermolecular nonsymmetrical Suzuki-Miyaura-type sp3-sp3 C-C bond formations between allyl carbonates and nontoxic allyl, allenyl, or propargyl boronates. This report represents the first use of these