1243809-81-5

Basic information

• Product Name: [Ga(CH[CMeN(2,6-iPr₂C₆H₃)]₂)(η²-P₄)]
• CAS NO: 1243809-81-5
• Molecular Weight: 611.276
• Mol File: 1243809-81-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ga(CH[CMeN(2,6-iPr₂C₆H₃)]₂)(η²-P₄)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ga(CH[CMeN(2,6-iPr₂C₆H₃)]₂)(η²-P₄)](1243809-81-5)
• EPA Substance Registry System: [Ga(CH[CMeN(2,6-iPr₂C₆H₃)]₂)(η²-P₄)](1243809-81-5)

Safety Data

• Hazardous Substances Data: 1243809-81-5(Hazardous Substances Data)

Upstream product

• 12185-10-3 phosphorous 
• 317322-17-1 [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)] 

Downstream Products

• 1243809-82-6 [Ga(2,4-bis(2,6-diisopropylphenylamino)-2-pentene)(η2:1:1-P4)(Mo(CO)5)2] 

Relevant articles and documents

P-P bond activation of P4 tetrahedron by group 13 carbenoid and its bis molybdenum pentacarbonyl adduct

Activation of white phosphorus with Ga(DDP) (DDP = 2-diiso- propylphenylamino-4-diiso-propylphenylimino-2-pentene) afforded [(DDP)Ga(P 4)] (1) by insertion of the Ga(I) center at one of the six P-P bonded edges of the P4 tetrahedron. Further reaction of 1 with three equivalents of Mo(CO)6 results in the formation of [(DDP)Ga(η2:1:1-P4){Mo(CO)5}2] 2toluene (2). Compounds 1 and 2 are characterized by 1H, 13C, and 31P NMR spectroscopy, elemental analysis, and single crystal X-ray structural analysis. The solid-state structure of molecule 1 reveals the first example of a structurally characterized GaP4 core stabilized by a β-diketiminate ligand. Compound 2 represents a rare type of coordination mode of a gallium supported P4 butterfly structure.