317322-17-1

Basic information

• Product Name: [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)]
• Synonyms: [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)]
• CAS NO: 317322-17-1
• Molecular Weight: 487.381
• Mol File: 317322-17-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)](317322-17-1)
• EPA Substance Registry System: [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)](317322-17-1)

Safety Data

• Hazardous Substances Data: 317322-17-1(Hazardous Substances Data)

Upstream product

• 334719-92-5 Dipp₂nacnacLi*Et₂O 
• 882530-05-4 [Ga₂C₅Me₅][B(C₆H₃(CF₃)2)4]*fluorobenzene 
• 7440-55-3 gallium 
• 223414-22-0 Li(2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃) 
• 7553-56-2 iodine 
• 141556-40-3 1,3,4,5-Tetramethylimidazol-2-yliden 
• 210832-39-6 N,N′-bis(2,6-diisopropylphenyl)pentane-2,4-diimine 

Downstream Products

• 1243809-81-5 [Ga(CH[CMeN(2,6-iPr₂C₆H₃)]₂)(η²-P₄)] 
• 1259037-70-1 [(CH((CMe)N(2,6-iPr₂C₆H₃))2Ga]2Ag[Al(OCH(CF₃)2)4] 
• 349545-05-7 (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂ 

Relevant articles and documents

Addressing the chemical sorcery of "GaI": Benefits of solid-state analysis aiding in the synthesis of P→Ga coordination compounds

The differing structures and reactivities of "GaI" samples prepared with different reaction times have been investigated in detail. Analysis by FT-Raman spectroscopy, powder X-ray diffraction, 71Ga solid-state NMR spectroscopy, and 127I nuclear quadrupole

Reductive elimination of [AlH2]+from a cationic Ga-Al dihydride

Oxidative addition of TMEDA-supported [AlH2]+to [{BDI}Ga] (BDI = {HC(C(CH3)N(2,6-iPr2-C6H3))2}) provides [{BDI}Ga(H)-Al(H)(tmeda)][B(C6H3-3,5-Me2)4] (TMEDA =N,N,N′N′-tetramethylethylenediamine) with a covalent metal-metal bond. The reaction is readily reversed by substituting TMEDA for an N-heterocyclic carbene or dissolving in THF.

A silicon–carbonyl complex stable at room temperature

Main-group-element compounds with energetically high-lying donor and low-lying acceptor orbitals are able to mimic chemical bonding motifs and reactivity patterns known in transition metal chemistry, including small-molecule activation and catalytic reactions. Monovalent group 13 compounds and divalent group 14 compounds, particularly silylenes, have been shown to be excellent candidates for this purpose. However, one of the most common reactions of transition metal complexes, the direct reaction with carbon monoxide and formation of room-temperature isolable carbonyl complexes, is virtually unknown in main-group-element chemistry. Here, we show the synthesis, single-crystal X-ray structure, and density functional theory computations of a room-temperature-stable silylene carbonyl complex [L(Br)Ga]2Si:–CO (L = HC[C(Me)N(2,6-iPr2-C6H3)]2), which was obtained by direct carbonylation of the electron-rich silylene intermediate [L(Br)Ga]2Si:. Furthermore, [L(Br)Ga]2Si:–CO reacts with H2 and PBr3 with bond activation, whereas the reaction with cyclohexyl isocyanide proceeds with CO substitution. [Figure not available: see fulltext.]