124572-59-4

Basic information

• Product Name: α-ionone epoxyhydrazone
• Synonyms: α-ionone epoxyhydrazone
• CAS NO: 124572-59-4
• Molecular Weight: 222.33
• Mol File: 124572-59-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: α-ionone epoxyhydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: α-ionone epoxyhydrazone(124572-59-4)
• EPA Substance Registry System: α-ionone epoxyhydrazone(124572-59-4)

Safety Data

• Hazardous Substances Data: 124572-59-4(Hazardous Substances Data)

Upstream product

• 37079-64-4 1-[3-(2,6,6-trimethyl-cyclohex-2-enyl)-oxiranyl]-ethanone 

Downstream Products

• 57549-92-5 ⁽²⁾-1-(2,6,6-trimethylcyclohex-2-en-1-yl)butan-1-one 
• 127-41-3 alpha-ionone 
• 28102-24-1 (Z)-2,6,6-Trimethyl-α-(1-propenyl)-2-cyclohexene-1-methanol 

Relevant articles and documents

NEW DEVELOPMENTS OF THE WHARTON TRANSPOSITION

The synthetically useful Wharton transposition can be improved by using a more adequate procedure in the critical step of the intermediate α-epoxyhydrazone cleavage.Either for stable hydrazones or unstable ones, the yield of the transposed allylic alcohol is increased by treatment under anhydrous conditions with highly basic reagents (KDA in the former case, NEt3 in the latter).