1246450-05-4

Basic information

• Product Name: 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II)
• Synonyms: 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II)
• CAS NO: 1246450-05-4
• Molecular Weight: 950.597
• Mol File: 1246450-05-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II)(CAS DataBase Reference)
• NIST Chemistry Reference: 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II)(1246450-05-4)
• EPA Substance Registry System: 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II)(1246450-05-4)

Safety Data

• Hazardous Substances Data: 1246450-05-4(Hazardous Substances Data)

Upstream product

• 187387-14-0 5,15-bis(3,5-di-tert-butylphenyl)porphyrin Zn^II 
• 349666-24-6 1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrene 
• 215313-78-3 [5,15-dibromo-10,20-bis-(3,5-di-tert-butyphenyl)porphyrinato]zinc(II) 
• 294183-84-9 (5-bromo-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II) 
• 187387-14-0 [5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) 

Downstream Products

• 1246450-06-5 {μ-[10,10'-bis(1-pyrenyl)-5,5',15,15'-tetrakis(3,5-di-tert-butylphenyl)-18,18',20,20'-dicyclo-2,2'-biporphyrinato(4-)-KN21,KN22,KN23,KN24,KN21',KN22',KN23',KN24']}dizinc(II) 
• 1353896-28-2 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)-10-bromoporphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II) 

Relevant articles and documents

FUSING PORPHYRINS WITH POLYCYCLIC AROMATIC HYDROCARBONS AND HETEROCYCLES FOR OPTOELECTRIC APPLICATIONS

A compound that can be used as a donor material in organic photovoltaic devices comprising a non-activated porphyrin fused with one or more non-activated polycyclic aromatic rings or one or more non-activated heterocyclic rings can be obtained by a thermal fusion process. By heating the reaction mixture of non-activated porphyrins with non-activated polycyclic aromatic rings or heterocyclic rings to a fusion temperature and holding for a predetermined time, fusion of one or more polycyciic rings or heterocyclic rings to the non-activated porphyrin core in meso,β fashion is achieved resulting in hybrid structures containing a distorted porphyrin ring with annulated aromatic rings. The porphyrin core can be olygoporphyrins.

Fused pyrene-diporphyrins: Shifting near-infrared absorption to 1.5 μm and beyond

(Figure Presented) Sticking together: Direct fusion of pyrene rings with diporphyrins can be achieved without prior activation of aromatic rings. This simple method gives pyrene-diporphyrin hybrids (see picture, C (pyrene) red, C (porphyrin) dark blue, N light blue, Zn green) with a high near-infrared (NIR) absorption that reaches the wavelengths required for use in telecommunications.