215313-78-3

Basic information

• Product Name: [5,15-dibromo-10,20-bis-(3,5-di-tert-butyphenyl)porphyrinato]zinc(II)
• Synonyms: [5,15-dibromo-10,20-bis-(3,5-di-tert-butyphenyl)porphyrinato]zinc(II)
• CAS NO: 215313-78-3
• Molecular Weight: 908.15
• Mol File: 215313-78-3.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: [5,15-dibromo-10,20-bis-(3,5-di-tert-butyphenyl)porphyrinato]zinc(II)(CAS DataBase Reference)
• NIST Chemistry Reference: [5,15-dibromo-10,20-bis-(3,5-di-tert-butyphenyl)porphyrinato]zinc(II)(215313-78-3)
• EPA Substance Registry System: [5,15-dibromo-10,20-bis-(3,5-di-tert-butyphenyl)porphyrinato]zinc(II)(215313-78-3)

Safety Data

• Hazardous Substances Data: 215313-78-3(Hazardous Substances Data)

Upstream product

• 187387-14-0 [5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) 
• 128-08-5 N-Bromosuccinimide 
• 187387-14-0 5,15-bis(3,5-di-tert-butylphenyl)porphyrin Zn^II 

Downstream Products

• 1039027-73-0 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II) 
• 1271735-32-0 [10,20-bis(3,5-di-tert-butylphenyl)-5-(3-benzothienyl)porphyrinato^(2-)-KN₂₁,KN₂₂,KN₂₃,KN₂₄]zinc(II) 
• 1271735-34-2 C₆₄H₅₆N₄S₂Zn 
• 1246450-05-4 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II) 
• 1246450-10-1 10,20-bis(3,5-di-tert-butylphenyl)-5,15-bis-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II) 
• 1271735-30-8 [10,20-bis(3,5-di-tert-butylphenyl)-5-(4,5-dimethoxyanthracen-1-yl)porphyrinato^(2-)-KN₂₁,KN₂₂,KN₂₃,KN₂₄]zinc(II) 
• 1271735-31-9 [10,20-bis(3,5-di-tert-butylphenyl)-5-(4,5-dimethoxyanthracen-9-yl)porphyrinato^(2-)-KN₂₁,KN₂₂,KN₂₃,KN₂₄]zinc(II) 
• 1352088-68-6 [10,20-bis-(3,5-di-tert-butylphenyl)-5,15-bis-(perylen-1-yl)-porphyrinato]zinc(II) 
• 1352088-72-2 [10,20-bis-(3,5-di-tert-butylphenyl)-5-(coronen-1-yl)porphyrinato]zinc(II) 
• 1352088-69-7 [10,20-bis-(3,5-di-tert-butylphenyl)-5,15-bis-(coronen-1-yl)-porphyrinato]zinc(II) 
• 1352088-67-5 [10,20-bis-(3,5-di-tert-butylphenyl)-5,15-bis-(naphth-1-yl)porphyrinato]zinc(II) 
• 1246450-10-1 [10,20-bis(3,5-di-tert-butylphenyl)-5,15-bis(1-pyrenyl)porphyrinato-(2-κN21,κN22,κN23,κN24)]zinc(II) 
• 1353896-27-1 10,20-bis(3,5-di-tert-butylphenyl)-5,15-bis(3-benzomienyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc (II) 
• 215313-77-2 zinc 5,15-bis(3,5-di-tert-butylphenyl)-10,20-bis(dicyanomethylene)porphyrin 

Relevant articles and documents

Basic Photophysical Properties of meso-Bis(pyren-2-yl)porphyrin: An Isomer of Pyrene-Substituted Porphyrins

The Suzuki-Miyaura coupling reaction of pyren-2-yl boronic acid ester with a meso-dibromodiphenylporphyrin derivative was carried out to give another pyrene-substituted porphyrin. The electrophilic substitution reaction occurred selectively on the porphyr

A quinoidal bis-phenalenyl-fused porphyrin with supramolecular organization and broad near-infrared absorption

A bis-phenalenyl-fused porphyrin has been synthesized by thermal dehydro-aromatization reaction regioselectively as a single syn-isomer. X-ray crystal structure revealed that both phenalenyl units of this porphyrin have close π-π contacts forming continuous network of interacting porphyrin rings. A broad and intense NIR absorption can be attributed to quinoidal character of bis-phenalenyl-fused porphyrin.

FUSING PORPHYRINS WITH POLYCYCLIC AROMATIC HYDROCARBONS AND HETEROCYCLES FOR OPTOELECTRIC APPLICATIONS

A compound that can be used as a donor material in organic photovoltaic devices comprising a non-activated porphyrin fused with one or more non-activated polycyclic aromatic rings or one or more non-activated heterocyclic rings can be obtained by a thermal fusion process. By heating the reaction mixture of non-activated porphyrins with non-activated polycyclic aromatic rings or heterocyclic rings to a fusion temperature and holding for a predetermined time, fusion of one or more polycyciic rings or heterocyclic rings to the non-activated porphyrin core in meso,β fashion is achieved resulting in hybrid structures containing a distorted porphyrin ring with annulated aromatic rings. The porphyrin core can be olygoporphyrins.