125423-96-3

Basic information

• Product Name: [(1R,4R)-1,7,7-Trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester
• CAS NO: 125423-96-3
• Molecular Weight: 347.541
• Mol File: 125423-96-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(1R,4R)-1,7,7-Trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [(1R,4R)-1,7,7-Trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(125423-96-3)
• EPA Substance Registry System: [(1R,4R)-1,7,7-Trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(125423-96-3)

Safety Data

• Hazardous Substances Data: 125423-96-3(Hazardous Substances Data)

Upstream product

• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 63254-60-4 (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl 2-aminoacetate 
• 120143-37-5 (1S,3S,4R)-menthyl glycinate 

Downstream Products

• 141033-86-5 (R)-3-(3,4-Dimethoxy-phenyl)-2-[(1R,4R)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2Z)-ylideneamino]-propionic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 
• 141033-86-5 (S)-3-(3,4-Dimethoxy-phenyl)-2-[(1R,4R)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2Z)-ylideneamino]-propionic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 
• 63-91-2 L-phenylalanine 
• 673-06-3 D-(R)-phenylalanine 
• 125424-01-3 2-[(1R,4R)-1,7,7-Trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-pent-4-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 125424-01-3 2-[(1R,4R)-1,7,7-Trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-pent-4-enoic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 
• 135999-87-0 (S)-3-Phenyl-2-[(1R,4R)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2Z)-ylideneamino]-propionic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 
• 141033-89-8 (S)-2-[(1R,4R)-1,7,7-Trimethyl-bicyclo[2.2.1]hept-(2Z)-ylideneamino]-hexanoic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 
• 138865-53-9 (R)-3-Methyl-2-[(1R,4R)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2Z)-ylideneamino]-butyric acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 
• 138865-53-9 (S)-3-Methyl-2-[(1R,4R)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2Z)-ylideneamino]-butyric acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 
• 141033-85-4 (R)-2-[(1R,4R)-1,7,7-Trimethyl-bicyclo[2.2.1]hept-(2Z)-ylideneamino]-pent-4-ynoic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 
• 141033-85-4 (S)-2-[(1R,4R)-1,7,7-Trimethyl-bicyclo[2.2.1]hept-(2Z)-ylideneamino]-pent-4-ynoic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 

Relevant articles and documents

ASYMMETRIC SYNTHESIS VII: DOUBLE STEREODIFFERENTATION IN ALLYLYTION OF KETIMINES BEARING TWO CHIRAL AUXILIARIES. APPLICATION TO ENANTIOSELECTIVE SYNTHESIS OF α-ALLYLGLYCINE

A diuble asymmetric induction has been observed in allylation of the imines derived from (+)-camphor, (+)- and (-)-2-hydroxypinan-3-ones with (+)- and (-)-menthyl glycinates.After hydrolysis of the allylated intermediates, (R)- and (S)-α-allylglycines are obtained in 3-90percent optical yields.