125990-08-1Relevant articles and documents
Br?nsted acid catalysis: Organocatalytic hydrogenation of imines
Rueping, Magnus,Azap, Cengiz,Sugiono, Erli,Theissmann, Thomas
, p. 2367 - 2369 (2005)
A new Br?nsted acid catalysed hydrogenation of imines with Hantzsch dihydropyridine as the hydrogen source has been developed. Diphenyl phosphate (DPP) and various other acids catalyse this first metal-free hydrogen transfer to give various amines under m
Nitrogen-Doped Carbon Enables Heterogeneous Asymmetric Insertion of Carbenoids into Amines Catalyzed by Rhodium Nanoparticles
Kobayashi, Shū,Masuda, Ryusuke,Yamashita, Yasuhiro,Yasukawa, Tomohiro
supporting information, p. 12786 - 12790 (2021/05/07)
Development of stable heterogeneous catalyst systems is a crucial subject to achieve sustainable society. Though metal nanoparticles are robust species, the study of asymmetric catalysis by them has been restricted because methods to activate metal nanopa
Visible-Light-Mediated Strategies to Assemble Alkyl 2-Carboxylate-2,3,3-Trisubstituted β-Lactams and 5-Alkoxy-2,2,4-Trisubstituted Furan-3(2H)-ones Using Aryldiazoacetates and Aryldiazoketones
Deflon, Victor M.,Dos Santos, Caio Y.,Gallo, Rafael D. C.,Jurberg, Igor D.,Munaretto, Laiéli S.,Okada, Celso Y.
supporting information, p. 9292 - 9296 (2021/12/06)
Two new visible-light-mediated strategies are described starting from aryldiazoacetates. The first approach describes their reaction with azides to afford the corresponding imines, and then reaction with aryldiazoketones produces alkyl 2-carboxylate-2,3,3