1263145-39-6Relevant articles and documents
Novel triphenylamine-based cyclometalated platinum(II) complexes for efficient luminescent oxygen sensing
Liu, Chun,Song, Xinlong,Rao, Xiaofeng,Xing, Yang,Wang, Zhonggang,Zhao, Jianzhang,Qiu, Jieshan
, p. 85 - 92 (2014)
Novel triphenylamine-based cyclometalated Pt(II) complexes containing a pyridyl moiety have been synthesized and fully characterized. The cyclometalating ligands were prepared via an efficient palladium-catalyzed ligand-free Suzuki reaction of 4-(diphenyl
Bis-cyclometalated Ir(III) complexes with a diphenylamino group: design, synthesis, and application in oxygen sensing
Liu, Chun,Yu, Hongcui,Rao, Xiaofeng,Lv, Xin,Jin, Zilin,Qiu, Jieshan
, p. 641 - 647 (2016/09/23)
A series of C?N type bis-cyclometalated Ir(III) complexes (Ir1-Ir4) with a diphenylamino group at the 4-position of the phenyl ring of 2-phenylpyridine (ppy) have been prepared and fully characterized. The influences of substituents (-H, -CH3,
Palladium-catalyzed ligand-free and aqueous Suzuki reaction for the construction of (hetero)aryl-substituted triphenylamine derivatives
Liu, Chun,Rao, Xiaofeng,Song, Xinlong,Qiu, Jieshan,Jin, Zilin
, p. 526 - 531 (2013/04/10)
This paper reports an efficient synthesis of triphenylamine (TPA) derivatives via a palladium-catalyzed Suzuki reaction of (hetero)aryl halides with 4-(diphenylamino)phenylboronic acid (DPBA) in aqueous ethanol under aerobic and ligand-free conditions. Heteroaryl halides, namely pyridyl bromides, quinolyl bromides, pyrimidinyl bromides, 2-chloropyrazine and sulfur-containing heteroaryl bromides, could react smoothly with DPBA, affording good to excellent yields under mild conditions. In addition, aryl bromides were also successfully employed in the cross-couplings with DPBA and furnished the products in high yields at room temperature. The cross-coupling of 4-bromobenzonitrile with DPBA gave the desired product in a quantitative yield within 2 min, resulting in a TOF up to 5820 h-1.