126399-03-9

Basic information

• Product Name: (E)-(S)-5-Methoxy-2,4-dimethyl-6-phenyl-hex-2-enoic acid ethyl ester
• CAS NO: 126399-03-9
• Molecular Weight: 276.376
• Mol File: 126399-03-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (E)-(S)-5-Methoxy-2,4-dimethyl-6-phenyl-hex-2-enoic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(S)-5-Methoxy-2,4-dimethyl-6-phenyl-hex-2-enoic acid ethyl ester(126399-03-9)
• EPA Substance Registry System: (E)-(S)-5-Methoxy-2,4-dimethyl-6-phenyl-hex-2-enoic acid ethyl ester(126399-03-9)

Safety Data

• Hazardous Substances Data: 126399-03-9(Hazardous Substances Data)

Upstream product

• 134440-89-4 (R)-3-Methoxy-2-methyl-4-phenyl-butyraldehyde 
• 21382-82-1 (carbethoxyethylidene)triphenylphosphorane 
• 134440-89-4 (2R,3S)-3-methoxy-2-methyl-4-phenylbutanal 

Downstream Products

• 126399-11-9 (2S,3S,4E)-6-bromo-2-methoxy-3,5-dimethyl-1-phenyl-4-hexene 
• 126456-06-2 (2S,3S,4E,6E,8S,9S)-3-amino-9-methoxy-2,6,8-trimethyl-10-phenyldeca-4,6-dienoic acid 
• 126399-08-4 (4E,6E)-(2S,3S,8S,9S)-3-Benzyloxycarbonylamino-9-methoxy-2,6,8-trimethyl-10-phenyl-deca-4,6-dienoic acid ethyl ester 
• 126399-06-2 (2E,4S,5S)-5-methoxy-2,4-dimethyl-6-phenylhex-2-enyl(triphenyl)phosphonium bromide 
• 134440-91-8 (2S,3S,8S,9S,4E,6Z)-3-(tert-butoxycarbonyl)amino-9-methoxy-2,6,8-trimethyl-10-phenyl-4,6-decadienoic acid methyl ester 
• 134440-91-8 (4Z,6E)-(2S,3S,8S,9S)-3-tert-Butoxycarbonylamino-9-methoxy-2,6,8-trimethyl-10-phenyl-deca-4,6-dienoic acid methyl ester 
• 134440-91-8 (4Z,6Z)-(2S,3S,8S,9S)-3-tert-Butoxycarbonylamino-9-methoxy-2,6,8-trimethyl-10-phenyl-deca-4,6-dienoic acid methyl ester 
• 126399-06-2 ((E)-(4S,5S)-5-Methoxy-2,4-dimethyl-6-phenyl-hex-2-enyl)-triphenyl-phosphonium; bromide 
• 134440-91-8 (2S,3S,8S,9S,4E,6E)-3-(tert-butoxycarbonyl)amino-9-methoxy-2,6,8-trimethyl-10-phenyl-4,6-decadienoic acid methyl ester 
• 134440-92-9 (2S,3S,4E,6E,8S,9S)-3-(tert-butoxycarbonyl)amino-9-methoxy-2,6,8-trimethyl-10-phenyl-4,6-decadienoic acid 
• 126399-11-9 cis/trans-(4S,5S)-1-bromo-5-methoxy-2,4-dimethyl-6-phenylhex-2-ene 
• 126399-05-1 (2E,4S,5S)-5-methoxy-2,4-dimethyl-6-phenylhex-2-en-1-ol 
• 126399-05-1 (Z)-(S)-5-Methoxy-2,4-dimethyl-6-phenyl-hex-2-en-1-ol 
• 126399-10-8 (E)-(4S,5R)-5-Methoxy-2,4-dimethyl-6-phenyl-hex-2-en-1-ol 

Relevant articles and documents

Stereocontrolled synthesis of (2S,3S,8S,9S)-3-amino-9-methoxy-2,6,8-trimethyl-10-phenyldeca-4E,6E-dienoic acid (ADDA), the characteristic amino acid of microcystins and nodularin

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Total synthesis of N-phthaloyl adda methyl ester: All stereocenters originating from a single chiral epoxyalcohol

Selective ring opening of (2S,3R)-epoxide of 4-benzyloxy-cis-2-buten-1-ol either at 2- or 3-position ensures stereospecific construction of all the chiral centers of Adda.