126741-67-1

Basic information

• Product Name: Silane, (1,1-dimethylethyl)-1-hexynyldiphenyl-
• CAS NO: 126741-67-1
• Molecular Formula: C22H28Si
• Molecular Weight: 320.55
• Mol File: 126741-67-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, (1,1-dimethylethyl)-1-hexynyldiphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,1-dimethylethyl)-1-hexynyldiphenyl-(126741-67-1)
• EPA Substance Registry System: Silane, (1,1-dimethylethyl)-1-hexynyldiphenyl-(126741-67-1)

Safety Data

• Hazardous Substances Data: 126741-67-1(Hazardous Substances Data)

Upstream product

• 693-02-7 hex-1-yne 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 16538-47-9 (Z)-1-iodohex-1-ene 
• 123628-93-3 2-<(1',1'-dimethylethyl)diphenylsilylmethyl>hexanal 
• 123628-87-5 (Z)-1-<(1',1'-dimethylethyl)diphenylsilyl>hex-1-ene 
• 96575-61-0 4-tert-butyl-1-(hex-1-ynyl)cyclohex-1-ene 

Relevant articles and documents

Iododesilylation of TIPS-, TBDPS-, and TBS-substituted alkenes in connection with the synthesis of amphidinolides B/D

The C-Si bonds of triisopropylsilyl-substituted alkenes, 1,3-dienes, and related multifunctional substrates, as well as analogous C-TBDPS and C-TBS bonds, are readily and chemoselectively cleaved with NIS (or other sources of I+, such as N-iodo

The Stereochemistry of Organometallic Compounds. XXXIV. Regioselection in the Hydroformylation of Silylalkenes

The regiochemistry of hydroformylation of alkenes can be controlled by use of bulky silyl groups attached to the alkene.Use of the t-butyldiphenylsilyl group leads to almost total regiocontrol and the method has been applied to the synthesis of aldols.