128854-14-8Relevant articles and documents
Indium-catalyzed allylation of imines with electrochemically assisted catalyst regeneration
Hilt, Gerhard,Smolko, Konstantin I.,Waloch, Christoph
, p. 1437 - 1439 (2002)
The chemo-electrochemical regeneration of low valent indium(I) reagents for Barbier-type carbon-carbon bond formation processes is described for several C=N double bond systems. The homoallylic amines are obtained in good yields from aniline-derived aldim
Chiral Br?nsted Acid-Catalyzed Metal-Free Asymmetric Direct Reductive Amination Using 1-Hydrosilatrane
Skrypai, Vladislav,Varjosaari, Sami E.,Azam, Fawwaz,Gilbert, Thomas M.,Adler, Marc J.
, p. 5021 - 5026 (2019)
The asymmetric direct reductive amination of prochiral ketones with aryl amines using 1-hydrosilatrane with a chiral Br?nsted acid catalyst is reported. This is the first known example of chiral Br?nsted acid-catalyzed asymmetric reductive amination using
Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: A dramatic effect of counteranions on reaction efficiency
Anderson, Laura L.,Arnold, John,Bergman, Robert G.
, p. 14542 - 14543 (2005)
The anilinium salt, [PhNH3][B(C6F5)4], has been identified as a catalyst for the hydroamination and hydroarylation of several different types of alkenes with anilines. The weakly coordinating counterion of this
Iron-catalysed hydroboration of non-activated imines and nitriles: Kinetic and mechanistic studies
Bazkiaei, Adineh Rezaei,Wiseman, Michael,Findlater, Michael
, p. 15284 - 15289 (2021/05/19)
Iron-catalysed hydroboration of imines and nitriles has been developed under low catalyst loading (1 mol%) in the presence of HBpin. A wide scope of substrate was found to smoothly undergo hydroboration, including electron releasing/withdrawing and haloge
Ruthenium N-Heterocyclic Carbene Complexes for Chemoselective Reduction of Imines and Reductive Amination of Aldehydes and Ketones
Kathuria, Lakshay,Samuelson, Ashoka G.
, (2020/06/17)
Chemoselective reduction of imines to secondary amines is catalyzed efficiently by tethered and untethered, half-sandwich ruthenium N-heterocyclic carbene (NHC) complexes at room temperature. The untethered Ru-NHC complexes are more efficient as catalysts for the reduction of aldimines and ketimines than the tethered complexes. Using the best untethered complex as a catalyst, electronic and steric demands on the reaction was probed using a series of imines. Chemoselectivity of the catalyst towards imine reduction was tested by performing inter and intramolecular competitive reactions in a variety of ways. The catalyst exhibits a very high TON and TOF under anaerobic conditions.
