1290086-52-0Relevant articles and documents
Fluorinated aromatic ketones as nucleophiles in the asymmetric organocatalytic formation of C-C and C-N bonds: A facile route to the construction of fluorinated quaternary stereogenic centers
Zhao, Yujun,Pan, Yuanhang,Liu, Hongjun,Yang, Yuanyong,Jiang, Zhiyong,Tan, Choon-Hong
, p. 3571 - 3574 (2011/05/05)
Highly enantioselective Mannich and α-amination reactions have been successfully developed using α-fluorinated aromatic ketones as fluorocarbon nucleophiles in the presence of a bicyclic chiral guanidine (see scheme; Ms=methanesulfonyl). This method is a