129436-54-0

Basic information

• Product Name: Diethyl-carbamic acid (1S,6R)-6-acetyl-3-methyl-cyclohex-2-enyl ester
• Synonyms: Diethyl-carbamic acid (1S,6R)-6-acetyl-3-methyl-cyclohex-2-enyl ester
• CAS NO: 129436-54-0
• Molecular Weight: 253.342
• Mol File: 129436-54-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Diethyl-carbamic acid (1S,6R)-6-acetyl-3-methyl-cyclohex-2-enyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Diethyl-carbamic acid (1S,6R)-6-acetyl-3-methyl-cyclohex-2-enyl ester(129436-54-0)
• EPA Substance Registry System: Diethyl-carbamic acid (1S,6R)-6-acetyl-3-methyl-cyclohex-2-enyl ester(129436-54-0)

Safety Data

• Hazardous Substances Data: 129436-54-0(Hazardous Substances Data)

Upstream product

• 78-94-4 methyl vinyl ketone 

Downstream Products

• 129436-56-2 2,6,10-Trimethyl-undeca-2,9-dien-6-ol 
• 129436-57-3 6-Methyl-2-[4-methyl-2-(4-methyl-pent-3-enyl)-cyclohex-3-enyl]-hept-5-en-2-ol 
• 129436-55-1 Diethyl-carbamic acid (1S,6R)-6-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-3-methyl-cyclohex-2-enyl ester 
• 129436-61-9 Diethyl-carbamic acid (1R,6S)-6-((R)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-cyclohex-2-enyl ester 
• 95602-94-1 (+/-)-Hernandulcin 
• 106882-17-1 (1S,6R)-6-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-3-methyl-cyclohex-2-enol 
• 115655-93-1 (R)-6-((R)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-cyclohex-2-enone 
• 129436-60-8 (R)-6-((R)-1-Hydroxy-1-methyl-pentyl)-3-methyl-cyclohex-2-enone 
• 129436-62-0 (1R,6S)-6-((R)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-cyclohex-2-enol 
• 129436-59-5 (1R,6S)-6-((R)-1-Hydroxy-1-methyl-pentyl)-3-methyl-cyclohex-2-enol 
• 129436-58-4 Diethyl-carbamic acid (1S,6R)-6-((S)-1-hydroxy-1-methyl-pentyl)-3-methyl-cyclohex-2-enyl ester 

Relevant articles and documents

O-1-(1,3-butadienyl) carbamates as diels-alder dienes: Stereospecific synthesis of (±)-Hernandulcin and congeners

The TiCl4-catalyzed addition of the title reactants to vinyl ketones regio- and stereospecifically yields cis-disubs, cyclohexenes which add RMgX stereospecifically to the ketone. A final product in this sequence is the intensely sweet sesquiterpene, hernandulcin.