95602-94-1Relevant articles and documents
Enantiospecific synthesis of (+)-hernandulcin
Gatti, Francesco G.
, p. 4997 - 4998 (2008/12/21)
The sesquiterpene (+)-hernandulcin has been enantiospecifically synthesized starting from (-)-neoisopulegol in seven steps and in 25% overall yield.
Synthesis of (+)-hernandulcin and (+)-epihernandulcin
Kim, Jung Hun,Lim, Hyun Jin,Cheon, Seung Hoon
, p. 4721 - 4722 (2007/10/03)
(+)-Hernandulcin 1, an extremely sweet bisabolane-type sesquiterpene, and (+)-epihernandulcin 2 were synthesized in six steps from (-)-isopulegol with 15 and 11 percent overall yields, respectively.
Synthesis of (+/-)-Hernandulcin by an Intramolecular Nitrile Oxide Cycloaddition Route from Farnesol
Zheng, Guo-Chi,Kakisawa, Hiroshi
, p. 602 - 604 (2007/10/02)
An intramolecular addition reaction of the nitrile oxide derived from (2Z,6E)-farnesal oxime afforded an isoxazoline derivative, which was converted into hernandulcin, a sweet sesquiterpene of Verbenaceae plant.