129849-05-4

Basic information

• Product Name: Methanesulfonic acid, trifluoro-, 2-acetylphenyl ester
• CAS NO: 129849-05-4
• Molecular Formula: C9H7F3O4S
• Molecular Weight: 268.213
• Mol File: 129849-05-4.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Methanesulfonic acid, trifluoro-, 2-acetylphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonic acid, trifluoro-, 2-acetylphenyl ester(129849-05-4)
• EPA Substance Registry System: Methanesulfonic acid, trifluoro-, 2-acetylphenyl ester(129849-05-4)

Safety Data

• Hazardous Substances Data: 129849-05-4(Hazardous Substances Data)

Upstream product

• 122-79-2 Phenyl acetate 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 118-93-4 o-hydroxyacetophenone 

Downstream Products

• 577-56-0 2-acetyl-benzoic acid 
• 58632-85-2 1-(2-butylphenyl)ethan-1-one 
• 103935-10-0 ethyl 2-acetylbenzoate 
• 1721-95-5 1,4-Dimethyl-isochinolin 
• 1372619-86-7 1-(3-phenylnaphthalen-1-yl)piperidine 
• 1372620-28-4 1-oxo-2-phenyl-1H-indene-3-carbaldehyde 
• 171258-08-5 2-(phenylethynyl)acetophenone 
• 1309688-79-6 C₂₃H₁₂F₅NO₂ 
• 1309688-89-8 C₁₆H₁₃N 
• 1202458-02-3 (E)-1-(2-(2-phenylethynyl)phenyl)ethanone oxime 
• 2142-64-5 1-(2-ethylphenyl)ethanone 
• 704-00-7 1,2-diacetylbenzene 
• 52095-40-6 o-acetylstyrene 

Relevant articles and documents

One-pot synthesis of 4-methylisoquinolines via a sequential Pd-catalyzed Heck reaction and intramolecular cyclization

An efficient, one-pot synthesis of 4-methylisoquinolines via a cascade Pd-catalyzed Heck reaction, intramolecular cyclization and isomerization has been developed. This reaction has a wide range of substrates with various functional groups, and the corresponding products have been obtained in good yields.

Synthesis of isoindole derivatives by palladium-catalyzed domino reaction of (2-alkynyl)phenylketone o-pentafluorobenzoyloximes

Isoindole derivatives were synthesized by the palladium-catalyzed cyclization of (2-alkynyl)phenylketone O-pentafluoro-benzoyloximes in the presence of organometallic compounds such as sodium formate and aryl boronic acid. Georg Thieme Verlag Stuttgart - New York.

Preparation and Palladium-Catalyzed Cross-Coupling of Aryl Triethylammonium Bis(catechol) Silicates with Aryl Triflates

Pentavalent aryl and heteroaryl bis(catechol) silicates undergo palladium-catalyzed cross-coupling with aryl and heteroaryl triflates in the presence of a fluoride source in excellent yields. These solid, air-stable bis(catechol) silicates are prepared from a high-yielding displacement reaction between catechol and an aryl siloxane in the presence of an amine base. The cross-coupling reaction is tolerant of a wide range of electron-donating and electron-withdrawing groups. Several examples of di-ortho-substituted triflates are successfully coupled with these reagents.