130252-83-4

Basic information

• Product Name: (S)-2-(4-Methoxy-benzyloxy)-1-((R)-2-methyl-oxiranyl)-ethanol
• Synonyms: (S)-2-(4-Methoxy-benzyloxy)-1-((R)-2-methyl-oxiranyl)-ethanol
• CAS NO: 130252-83-4
• Molecular Weight: 238.284
• Mol File: 130252-83-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-2-(4-Methoxy-benzyloxy)-1-((R)-2-methyl-oxiranyl)-ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-(4-Methoxy-benzyloxy)-1-((R)-2-methyl-oxiranyl)-ethanol(130252-83-4)
• EPA Substance Registry System: (S)-2-(4-Methoxy-benzyloxy)-1-((R)-2-methyl-oxiranyl)-ethanol(130252-83-4)

Safety Data

• Hazardous Substances Data: 130252-83-4(Hazardous Substances Data)

Upstream product

• 130252-82-3 1-p-methoxybenzyloxy-3-methylbut-3-en-2-ol 
• 824-94-2 p-methoxybenzyl chloride 
• 121289-23-4 p-methoxybenzyloxyacetaldehyde 
• 14289-62-4 1-(allyloxymethyl)-4-methoxybenzene 
• 170421-35-9 (2R,3R)-2,3-epoxy-4-(4-methoxyphenyl)methoxy-2-methylbutanol 

Downstream Products

• 130252-84-5 (2R,3S)-3,4-epoxy-1-(4-methoxyphenyl)methoxy-3-methylbutan-2-yl 3-methoxy-5-methyl-1-naphthoate 

Relevant articles and documents

Synthetic studies of carzinophilin. Part 1: Synthesis of 2-methylidene-1-azabicyclo[3.1.0]hexane systems related to carzinophilin

Synthesis of the model compounds of carzinophilin carrying 2-methylidene-1-aza-bicyclo[3.1.0]hexane systems was achieved. Formation of malonylidenes or N-acyl-glycinylidenepyrrolidines was carried out by utilizing Eschenmoser's sulfide contraction or Herdeis's condensation between the 2-methylthio-Δ1-pyrrolone derivatives and ethyl nitroacetate, respectively. The 1-azabicyclo-[3.1.0]hexane systems were constructed by base-promoted aziridine formation.