130840-94-7

Basic information

• Product Name: Benzene, 1,1'-(1,2-ethanediyl)bis[2-(chloromethyl)-4-(1,1-dimethylethyl)-
• CAS NO: 130840-94-7
• Molecular Formula: C24H32Cl2
• Molecular Weight: 391.424
• Mol File: 130840-94-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1,2-ethanediyl)bis[2-(chloromethyl)-4-(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1,2-ethanediyl)bis[2-(chloromethyl)-4-(1,1-dimethylethyl)-(130840-94-7)
• EPA Substance Registry System: Benzene, 1,1'-(1,2-ethanediyl)bis[2-(chloromethyl)-4-(1,1-dimethylethyl)-(130840-94-7)

Safety Data

• Hazardous Substances Data: 130840-94-7(Hazardous Substances Data)

Upstream product

• 194666-01-8 4,4'-di-tert-butyl-2,2'-dibromodiphenylethane 
• 246139-76-4 2-bromo-1-(bromomethyl)-4-(tert-butyl)benzene 
• 61024-94-0 2-bromo-4-tert-butyl-1-methylbenzene 
• 194665-97-9 {5-tert-Butyl-2-[2-(4-tert-butyl-2-hydroxymethyl-phenyl)-ethyl]-phenyl}-methanol 

Downstream Products

• 159585-56-5 4,4'-di-tert-butyl-2,2'-dimethyldiphenylethane 

Relevant articles and documents

Selective Preparation of Polycyclic Aromatic Hydrocarbons. Part 7. A Preparative Route to 10,11-Dihydro-5H-dibenzo-cycloheptenes Using Friedel-Crafts Intramolecular Cyclobenzylation

Cyclobenzylation of 2-hydroxymethyldiphenylethanes 4 and 2,2'-bis(hydroxymethyl)diphenylethanes 13 in the presence of a solid perfluorinated sulfonic acid resin, Nafion-H, as a catalyst results in novel polycyclic aromatic hydrocarbons, dibenzocyclopentenes.Dibenzocyclopentenes were also prepared from diphenylethanes by a benzylation reaction, which incorporates chloromethylation of a hydrocarbon followed by Friedel-Crafts intramolecular cyclization reaction.The present method involving the action of ClCH2OMe and TiCl4 on a variety of diphenylethanes (constructed such that electrophilic substitution occurs ortho to the diphenylethane linkage) offers a convenient, mild one-pot synthesis of substituted dibenzocycloheptenes.The mechanism of these reactions is also discussed.