1309661-67-3

Basic information

• Product Name: (-)-(1S,6R)-methyl-6-((tert-butyldimethylsilyl)oxy)-1-hydroxycyclohexa-2,4-dienecarboxylate
• Synonyms: (-)-(1S,6R)-methyl-6-((tert-butyldimethylsilyl)oxy)-1-hydroxycyclohexa-2,4-dienecarboxylate
• CAS NO: 1309661-67-3
• Molecular Weight: 284.428
• Mol File: 1309661-67-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (-)-(1S,6R)-methyl-6-((tert-butyldimethylsilyl)oxy)-1-hydroxycyclohexa-2,4-dienecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(1S,6R)-methyl-6-((tert-butyldimethylsilyl)oxy)-1-hydroxycyclohexa-2,4-dienecarboxylate(1309661-67-3)
• EPA Substance Registry System: (-)-(1S,6R)-methyl-6-((tert-butyldimethylsilyl)oxy)-1-hydroxycyclohexa-2,4-dienecarboxylate(1309661-67-3)

Safety Data

• Hazardous Substances Data: 1309661-67-3(Hazardous Substances Data)

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 172877-72-4 (-)-(1S,6R)-methyl 1,6-dihydroxycyclohexa-2,4-dienecarboxylate 
• 532-32-1 sodium benzoate 
• 32359-20-9 (1S,2R)-1,2-dihydroxycyclohexa-3,5-diene-1-carboxylic acid 

Relevant articles and documents

Total synthesis of (+)-grandifloracin by iron complexation of a microbial arene oxidation product

(+)-Grandifloracin was synthesized from sodium benzoate by means of a dearomatizing dihydroxylation that proceeds with unusual regioselectivity. Iron diene complexes formed from the arene oxidation product permit the use of otherwise inaccessible transfor

A Formal Approach to Xylosmin and Flacourtosides E and F: Chemoenzymatic Total Synthesis of the Hydroxylated Cyclohexenone Carboxylic Acid Moiety of Xylosmin

The hydroxylated cyclohexenone carboxylic acid moiety of xylosmin was synthesized in eight steps from benzoic acid. The key steps in the synthesis involved the enzymatic dihydroxylation of benzoic acid by the whole cell fermentation with Ralstonia eutroph