1311029-92-1

Basic information

• Product Name: {bis-(2,8-di-(m-bromophenyl)-1-aza-3,7-dioxabicyclo[3.3.0]-octane 5-methoxy)methyl}-3-bromobenzene
• CAS NO: 1311029-92-1
• Molecular Weight: 1077.3
• Mol File: 1311029-92-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {bis-(2,8-di-(m-bromophenyl)-1-aza-3,7-dioxabicyclo[3.3.0]-octane 5-methoxy)methyl}-3-bromobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: {bis-(2,8-di-(m-bromophenyl)-1-aza-3,7-dioxabicyclo[3.3.0]-octane 5-methoxy)methyl}-3-bromobenzene(1311029-92-1)
• EPA Substance Registry System: {bis-(2,8-di-(m-bromophenyl)-1-aza-3,7-dioxabicyclo[3.3.0]-octane 5-methoxy)methyl}-3-bromobenzene(1311029-92-1)

Safety Data

• Hazardous Substances Data: 1311029-92-1(Hazardous Substances Data)

Upstream product

• 1185-53-1 tris hydrochloride 
• 1122-91-4 4-bromo-benzaldehyde 

Relevant articles and documents

Synthesis and ring-chain-ring tautomerism of bisoxazolidines, thiazolidinyloxazolidines, and spirothiazolidines

The synthesis of fused heterocycles such as thiazolidinyl-oxazolidine 3 is described starting from Tris·HCl. The mercaptomethyl bisoxazolidine 8 was found to convert to the corresponding thiazolidinyloxazolidine 3 and the spiro-heterocycle 4 by a ring-chain-ring tautomerism, depending on the electronic nature of the ring substituents as well as the reaction conditions. This equilibration pathway is absent in the hydroxymethyl bisoxazolidines 2. Computational studies confirm that both kinetic and thermodynamic control features play a role in the product distribution.