1311297-12-7Relevant articles and documents
Lewis-base stabilized diiodine adducts with N-heterocyclic chalcogenamides
Tretiakov, Mykyta,Shermolovich, Yuriy G.,Singh, Amit Pratap,Samuel, Prinson P.,Roesky, Herbert W.,Niepoetter, Benedikt,Visscher, Arne,Stalke, Dietmar
, p. 12940 - 12946 (2013)
Oxidation reactions of stable chalcogenamides with iodine are intriguing due to their broad application in various organic syntheses. In the present study we report on the utilization of N-heterocyclic carbene and cyclic-alkyl-amino carbenes L1-3/su
Saturated NHC Derived Dichalcogen Dications
Rottsch?fer, Dennis,Fuhs, Désirée E.,Neumann, Beate,Stammler, Hans-Georg,Ghadwal, Rajendra S.
, p. 574 - 579 (2020)
Herein, the synthesis and characterization of dicationic dichalcogenide compounds [(SIPr)E]2(OTf)2 (3a-E) (E = S, Se, Te) based on a saturated N-heterocyclic carbene (NHC), SIPr [SIPr = C{N(Dipp)CH2}2, Dipp = 2,
A Mechanistically and Operationally Simple Route to Metal–N-Heterocyclic Carbene (NHC) Complexes
Cavallo, Luigi,Cazin, Catherine S. J.,Collado, Alba,Collett, Christopher J.,Falivene, Laura,Nahra, Fady,Nolan, Steven P.,Saab, Marina,Smith, Andrew D.,Tzouras, Nikolaos V.,Van Hecke, Kristof
supporting information, (2020/03/24)
We have been puzzled by the involvement of weak organic and inorganic bases in the synthesis of metal–N-heterocyclic carbene (NHC) complexes. Such bases are insufficiently strong to permit the presumed required deprotonation of the azolium salt (the carbe