258278-25-0 Usage
Description
1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE is a white to yellow crystalline powder that is used in the efficient, one-pot synthesis of N-heterocyclic carbene-allylpalladium complexes. It is a valuable compound in the field of organic chemistry due to its unique chemical properties and potential applications.
Uses
Used in Organic Chemistry:
1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE is used as a key intermediate in the synthesis of N-heterocyclic carbene-allylpalladium complexes for its ability to facilitate efficient one-pot reactions.
Used in Pharmaceutical Industry:
1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE is used as a catalyst or reagent in the development of new pharmaceutical compounds, leveraging its unique chemical properties to enhance the synthesis process and improve the overall yield of desired products.
Used in Material Science:
In the field of material science, 1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE is used as a component in the creation of novel materials with specific properties, such as improved stability or reactivity, due to its unique molecular structure.
Used in Research and Development:
1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE is employed as a research tool in academic and industrial laboratories to explore new reaction pathways, develop innovative synthetic methods, and understand the underlying mechanisms of complex chemical transformations.
Check Digit Verification of cas no
The CAS Registry Mumber 258278-25-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,5,8,2,7 and 8 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 258278-25:
(8*2)+(7*5)+(6*8)+(5*2)+(4*7)+(3*8)+(2*2)+(1*5)=170
170 % 10 = 0
So 258278-25-0 is a valid CAS Registry Number.
InChI:InChI=1/C27H39N2.ClH/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;/h9-14,17-21H,15-16H2,1-8H3;1H/q+1;/p-1
258278-25-0Relevant articles and documents
Application of Quantitative 1H and 19F NMR to Organometallics
Akhdar, Ayman,Andanson, Jean-Michel,Faure, Sophie,Gautier, Arnaud,Tra?kia, Mounir
, (2021/08/03)
Purity assessment of organometallics is particularly important for catalytic applications. While quantitative NMR is a well-known method in pharmaceutic chemistry, the present work illustrates its usefulness for the determination of the ligands and organometallics purities using proton and fluorine NMR. This method is fast, straightforward and provides accuracy results.
Synthesis of Imidazolidinone, Imidazolone, and Benzimidazolone Derivatives through Oxidation Using Copper and Air
Li, Dazhi,Ollevier, Thierry
supporting information, p. 3572 - 3575 (2019/05/24)
A new synthetic method of urea derivatives using copper and air was developed. These mild conditions provided moderate to very good yields for 15 examples (53-93%), while low yields were obtained with sterically hindered substrates (3 examples). The reaction was found to go through an in situ generated copper-N-heterocyclic carbene, which was then oxidized into cyclic urea derivatives possessing alkyl, benzyl, aryl, hydroxy, Boc-protected, and tertiary amine groups.
Oxygen-atom insertion of NHCecopper complex: The source of oxygen from N, N-dimethylformamide
Zeng, Wei,Wang, Enyu,Qiu, Rui,Sohail, Muhammad,Wu, Shaoxiang,Chen, Fu-Xue
supporting information, p. 44 - 48 (2013/10/08)
An unprecedented protocol for oxygen-atom insertion reaction of NHCecopper complexes has been developed by employing N,N-dimethylformamide as the oxygen source, which allows the preparation of imidazolinones from carbene complexes and decodes one of the m