13126-70-0 Usage
General Description
Silver formate is a chemical compound with the formula Ag(HCOO), consisting of a silver cation and a formate anion. It is a colorless and odorless crystalline solid, and is water-soluble. Silver formate is often used in organic synthesis as a catalyst for various reactions, and it can also be used in the preparation of other silver compounds. It is considered to be moderately toxic and can cause irritation to the skin and eyes upon contact. Additionally, it is important to handle silver formate with caution as it is sensitive to light and heat, and can decompose to produce toxic gases. Overall, silver formate is a versatile compound with various applications in chemical synthesis and can be useful in a controlled laboratory setting.
Check Digit Verification of cas no
The CAS Registry Mumber 13126-70-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,1,2 and 6 respectively; the second part has 2 digits, 7 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 13126-70:
(7*1)+(6*3)+(5*1)+(4*2)+(3*6)+(2*7)+(1*0)=70
70 % 10 = 0
So 13126-70-0 is a valid CAS Registry Number.
13126-70-0Relevant articles and documents
Deniges, G.
, p. 1 - 4 (1938)
Synthesis and properties of (π-allyl)palladium formates as intermediates in palladium-catalyzed reductive cleavage of allylic acetates and carbonates with formic acid
Oshima, Masato,Shimizu, Isao,Yamamoto, Akio,Ozawa, Fumiyuki
, p. 1221 - 1223 (2008/10/08)
Neutral (π-allyl)(tertiary phosphine)palladium formates and ionic (π-allyl)bis(tertiary phosphine)palladium formates that are regarded as key intermediates in palladium-catalyzed reductive cleavage of allylic acetates and carbonates with formic acid have been prepared and characterized by 1H and 13C NMR spectroscopy. From a study of the formation process of these formate intermediates by anion exchange of the acetate anion with formic acid and by establishment of the course of liberation of olefins and CO2 from the formate ligand, the validity of the proposed catalytic cycle has been substantiated.
