1315248-52-2

Basic information

• Product Name: 2-methyl-6-trimethylsilanylethynylquinoline
• Synonyms: 2-methyl-6-trimethylsilanylethynylquinoline
• CAS NO: 1315248-52-2
• Molecular Weight: 239.392
• Mol File: 1315248-52-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-methyl-6-trimethylsilanylethynylquinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-6-trimethylsilanylethynylquinoline(1315248-52-2)
• EPA Substance Registry System: 2-methyl-6-trimethylsilanylethynylquinoline(1315248-52-2)

Safety Data

• Hazardous Substances Data: 1315248-52-2(Hazardous Substances Data)

Upstream product

• 877-42-9 6-Bromo-2-methyl-quinoline 
• 1066-54-2 trimethylsilylacetylene 

Downstream Products

• 1233505-71-9 6-ethynyl-2-methylquinoline 

Relevant articles and documents

Catalytic Anti-Markovnikov Hydroallylation of Terminal and Functionalized Internal Alkynes: Synthesis of Skipped Dienes and Trisubstituted Alkenes

We have developed catalytic anti-Markovnikov hydroallylation of terminal and functionalized internal alkynes. In this article, we describe the development of the reaction, exploration of the substrate scope, and a study of the reaction mechanism. Synthesis of skipped dienes through the hydroallylation of terminal alkyl and aryl alkynes with simple allyl phosphates and 2-substituted allyl phosphates is described. The hydroallylation of functionalized internal alkynes leads to the formation of skipped dienes containing trisubstituted alkenes. We demonstrate that the hydroallylation of internal alkynes can be used in the regio- and diastereoselective synthesis of complex trisubstituted alkenes. A mechanism of the hydroallylation reaction is proposed, and experimental evidence is provided for the key steps of the catalytic cycle. Stoichiometric experiments demonstrate an unexpected role of lithium alkoxide in the carbon-carbon bond-forming step of the reaction. A study of the hydrocupration of internal alkynes provides new insight into the structure, stability, and reactivity of alkenyl copper intermediates, as well as insight into the source of the regioselectivity in reactions of internal alkynes.

MULTIPHOTON ACTIVABLE QUINOLINE DERIVATIVES, THEIR PREPARATION AND THEIR USES

The present invention relates to multiphoton activable organic compounds responding to the following formula (I). The present invention also relates to a method of synthesizing the compounds of the invention, to an aqueous solution comprising at least one compound of the invention, and to their specific uses. The present invention also concerns a method of liberating organic ligands, said method involving the step of irradiating a compound according to the invention.