1325714-24-6

Basic information

• Product Name: ethyl 4-formyl-2-(4-(trifluoromethyl)phenyl)-1H-pyrrole-3-carboxylate
• Synonyms: ethyl 4-formyl-2-(4-(trifluoromethyl)phenyl)-1H-pyrrole-3-carboxylate
• CAS NO: 1325714-24-6
• Molecular Weight: 311.26
• Mol File: 1325714-24-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 4-formyl-2-(4-(trifluoromethyl)phenyl)-1H-pyrrole-3-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 4-formyl-2-(4-(trifluoromethyl)phenyl)-1H-pyrrole-3-carboxylate(1325714-24-6)
• EPA Substance Registry System: ethyl 4-formyl-2-(4-(trifluoromethyl)phenyl)-1H-pyrrole-3-carboxylate(1325714-24-6)

Safety Data

• Hazardous Substances Data: 1325714-24-6(Hazardous Substances Data)

Upstream product

• 106263-53-0 ethyl 3-oxo-3-(4-(trifluoromethyl)phenyl)propanoate 
• 1325713-83-4 (Z)-ethyl 3-(allylamino)-3-(4-(trifluoromethyl)phenyl)acrylate 

Relevant articles and documents

Copper-mediated aerobic synthesis of 3-azabicyclo[3.1.0]hex-2-enes and 4-carbonylpyrroles from N-allyl/propargyl enamine carboxylates

Synthetic methods for 3-azabicyclo[3.1.0]hex-2-enes and 4-carbonylpyrroles have been developed that use copper-mediated/catalyzed reactions of N-allyl/propargyl enamine carboxylates under an O2 atmosphere and involve intramolecular cyclopropanation and carbooxygenation, respectively. These methodologies take advantage of orthogonal modes of chemical reactivity of readily available N-allyl/propargyl enamine carboxylates; the complementary pathways can be accessed by slight modification of the reaction conditions.