134513-03-4

Basic information

• Product Name: (R)-1-(Toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid (1S,2R,5S)-2,5-dimethyl-bicyclo[3.2.0]hept-2-yl ester
• CAS NO: 134513-03-4
• Molecular Weight: 391.532
• Mol File: 134513-03-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-1-(Toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid (1S,2R,5S)-2,5-dimethyl-bicyclo[3.2.0]hept-2-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-(Toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid (1S,2R,5S)-2,5-dimethyl-bicyclo[3.2.0]hept-2-yl ester(134513-03-4)
• EPA Substance Registry System: (R)-1-(Toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid (1S,2R,5S)-2,5-dimethyl-bicyclo[3.2.0]hept-2-yl ester(134513-03-4)

Safety Data

• Hazardous Substances Data: 134513-03-4(Hazardous Substances Data)

Upstream product

• 54731-09-8 N-tosyl-L-prolyl chloride 
• 73416-58-7 2,5-dimethylbicyclo<3.2.0>heptan-endo-2-ol 
• 132957-48-3 (1S,2R,5S)-(+)-2,5-dimethylbicyclo<3.2.0>heptan-endo-2-ol 
• 118776-39-9 (2R)-(+)-1-(4-toluenesulphonyl)prolyl chloride 
• 67604-72-2 (4R)-4-methyl-4-trimethylsilyloxyhex-5-enal 
• 126-90-9 (S)-(+)-linalool 
• 132957-49-4 (1R,2S,5R)-(-)-2,5-dimethylbicyclo<3.2.0>heptan-endo-2-ol 
• 134624-65-0 (3S)-3,6-dimethylhepta-1,6-dien-3-ol 
• 134624-67-2 (3R)-3,6-dimethylhepta-1,6-dien-3-ol 
• 134513-03-4 (S)-1-(Toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid (1R,2S,5R)-2,5-dimethyl-bicyclo[3.2.0]hept-2-yl ester 
• 134513-08-9 (3S)-3,6-dimethyl-3-trimethylsilyloxyhepta-1,6-diene 
• 134513-03-4 (S)-1-(Toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid (1S,2R,5S)-2,5-dimethyl-bicyclo[3.2.0]hept-2-yl ester 
• 134513-03-4 (R)-1-(Toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid (1S,2R,5S)-2,5-dimethyl-bicyclo[3.2.0]hept-2-yl ester 
• 67604-71-1 (R)-((3,7-dimethylocta-1,6-dien-3-yl)oxy)trimethylsilane 

Downstream Products

• 55456-48-9 ((2S)-1-p-toluenesulfonyl-2-pyrrolidinyl)methanol 
• 134513-03-4 (R)-1-(Toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid (1S,2R,5S)-2,5-dimethyl-bicyclo[3.2.0]hept-2-yl ester 
• 134513-03-4 (R)-1-(Toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid (1R,2S,5R)-2,5-dimethyl-bicyclo[3.2.0]hept-2-yl ester 
• 134513-03-4 (S)-1-(Toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid (1S,2R,5S)-2,5-dimethyl-bicyclo[3.2.0]hept-2-yl ester 
• 134513-04-5 [1-(toluene-4-sulfonyl)-pyrrolidin-2-yl]-methanol 
• 132957-48-3 (1S,2R,5S)-(+)-2,5-dimethylbicyclo<3.2.0>heptan-endo-2-ol 
• 132957-49-4 (1R,2S,5R)-(-)-2,5-dimethylbicyclo<3.2.0>heptan-endo-2-ol 

Relevant articles and documents

Resolution and EPC Synthesis of Both Enantiomers of 2,5-Dimethylbicycloheptan-endo-2-ol, Key Intermediate in the Synthesis of Grandisol.

The pure enantiomers of 2,5-dimethylbicycloheptan-endo-2-ol, key intermediate in the synthesis of grandisol, have been conveniently prepared by optical resolution with (2S)-(-)- and (2R)-(+)-1-(4-toluenesulphonyl)pyrrolidine-2-carboxylic acid chlor