1345511-83-2

Basic information

• Product Name: (E)-1,3-bis(3,5-difluorophenyl)prop-2-en-1-ol
• CAS NO: 1345511-83-2
• Molecular Weight: 282.237
• Mol File: 1345511-83-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1,3-bis(3,5-difluorophenyl)prop-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1,3-bis(3,5-difluorophenyl)prop-2-en-1-ol(1345511-83-2)
• EPA Substance Registry System: (E)-1,3-bis(3,5-difluorophenyl)prop-2-en-1-ol(1345511-83-2)

Safety Data

• Hazardous Substances Data: 1345511-83-2(Hazardous Substances Data)

Upstream product

• 123577-99-1 3′,5′-difluoroacetophenone 
• 32085-88-4 3,5-difluorobenzaldehyde 
• 461-96-1 3,5-difluorobromobenzene 
• 1345511-82-1 (E)-1,3-bis(3,5-difluorophenyl)prop-2-en-1-one 

Relevant articles and documents

Electrophilicities of symmetrically substituted 1,3-diarylallyl cations

Kinetics of the reactions of nine symmetrically substituted 1,3-diarylallyl cations with different nucleophiles were studied photometrically in dichloromethane, acetonitrile, and DMSO solutions. The second-order rate constants k2 were found to follow the correlation log k2 = sN(N + E). The electrophilicity parameters E of the title cations were derived, using the known values of sN and N of the nucleophilic reaction partners, and compared with the electrophilicities of analogously substituted benzhydrylium ions. Good linear correlations were found between the electrophilicities E and the quantum chemically calculated gas-phase methyl anion affinities of the allyl cations and the σ+ constants of the substituents X.