1345959-46-7Relevant articles and documents
Photorelease of primary aliphatic and aromatic amines by visible-light-induced electron transfer
Edson, Joseph B.,Spencer, Liam P.,Boncella, James M.
, p. 6156 - 6159 (2012/01/05)
Visible-light-absorbing tris(bipyridyl)ruthenium(II) has been used to mediate electron transfer to N-methylpicolinium carbamates that undergo C-O bond fragmentation followed by spontaneous carbon dioxide release to give free amines. Release of several aliphatic and aromatic primary amines has been demonstrated under mild conditions using visible light.