135005-24-2

Basic information

• Product Name: Silane, [(4-ethenylphenyl)ethynyl]trimethyl-
• CAS NO: 135005-24-2
• Molecular Formula: C13H16Si
• Molecular Weight: 200.356
• Mol File: 135005-24-2.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Silane, [(4-ethenylphenyl)ethynyl]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(4-ethenylphenyl)ethynyl]trimethyl-(135005-24-2)
• EPA Substance Registry System: Silane, [(4-ethenylphenyl)ethynyl]trimethyl-(135005-24-2)

Safety Data

• Hazardous Substances Data: 135005-24-2(Hazardous Substances Data)

Upstream product

• 2039-82-9 1-bromo-4-ethenyl-benzene 
• 1066-54-2 trimethylsilylacetylene 
• 1122-91-4 4-bromo-benzaldehyde 
• 6396-08-3 triphenylphosphine hydrogen iodide 
• 77123-57-0 4-[(trimethylsilyl)ethynyl]bezaldehyde 

Downstream Products

• 393857-27-7 (2-(4-ethylphenyl)ethynyl)trimethylsilane 
• 1193111-10-2 (Z)-3-acetyl-4-(4-ethenylphenyl)-2,4-pentadien-2-ol 
• 915380-21-1 ethoxy(di-(1-methylethyl))-2-[4-[(E)-2-(ethoxydimethylsilyl)ethenyl]phenyl]ethenylsilane 
• 915380-20-0 Ethoxy-diisopropyl-[(E)-2-(4-vinyl-phenyl)-vinyl]-silane 
• 2499-64-1 4-ethynylstyrene 

Relevant articles and documents

Synthesis of Enantiopure C3-Symmetric Triangular Molecules

An asymmetric synthesis of C3-symmetric triangular macrocycles is reported. 1-Methylsulfonyl-4-(4-vinylphenyl)-1,2,3-triazole undergoes a rhodium(II)-catalyzed cyclotrimerization to establish an enantiopure C3-symmetric triangular ma

Zinc-Catalysed Hydroboration of Terminal and Internal Alkynes

A regioselective hydroboration of alkynes has been developed by using commercially available zinc triflate as a catalyst, in the presence of catalytic amount of NaBHEt3. The reaction tolerates a wide range of terminal alkynes having several synthetically useful functional groups and proceeds regioselectively to furnish hydroborated products in moderate to excellent yields. This system shows moderate chemoselectivity towards terminal C≡C bond over terminal and internal C=C bond and internal C≡C bond.

Nickel-Catalyzed Highly Regioselective Hydrocyanation of Terminal Alkynes with Zn(CN)2 Using Water as the Hydrogen Source

The first efficient and general nickel-catalyzed hydrocyanation of terminal alkynes with Zn(CN)2 in the presence of water has been developed. The reaction provides a regioselective protocol for the synthesis of functionalized vinyl nitriles with a range of structural diversity under mild reaction conditions while obviating use of the volatile and hazardous reagent of HCN. Deuterium-labeling experiments confirmed the role of water as the hydrogen source in this hydrocyanation reaction.