1357495-82-9

Basic information

• Product Name: benzyl 2-(6-oxo-2,4,5,6-tetrahydrocyclopenta[c]pyrrol-4-yl)-acetate
• Synonyms: benzyl 2-(6-oxo-2,4,5,6-tetrahydrocyclopenta[c]pyrrol-4-yl)-acetate
• CAS NO: 1357495-82-9
• Molecular Weight: 269.3
• Mol File: 1357495-82-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl 2-(6-oxo-2,4,5,6-tetrahydrocyclopenta[c]pyrrol-4-yl)-acetate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 2-(6-oxo-2,4,5,6-tetrahydrocyclopenta[c]pyrrol-4-yl)-acetate(1357495-82-9)
• EPA Substance Registry System: benzyl 2-(6-oxo-2,4,5,6-tetrahydrocyclopenta[c]pyrrol-4-yl)-acetate(1357495-82-9)

Safety Data

• Hazardous Substances Data: 1357495-82-9(Hazardous Substances Data)

Upstream product

• 38622-91-2 [(p-methylphenyl)sulfonylmethyl]isonitrile 
• 158604-58-1 benzyl 2-(4-oxocyclopent-2-en-1-yl)acetate 
• 74877-21-7 2-(4-oxocyclopent-2-en-1-yl)acetic acid 
• 13173-09-6 bicyclo[3.2.0]hept-2-en-6-one 
• 56011-39-3 (1R*,2S*,3S*,5R*)-(±)-2-bromo-3-hydroxybicyclo[3.2.0]heptan-6-one 
• 68372-66-7 1β,5β,7α,-7-hydroxy-2-oxabicyclo<3.3.0>octan-3-one 

Relevant articles and documents

Synthesis of 3,4-fused cycloalkanopyrroles by 1,3-dipolar cycloaddition

The synthesis of a number of 3,4-fused cycloalkanopyrroles bearing substituents on the cycloalkane ring was accomplished by 1,3-dipolar cycloaddition. The yield of the cyclization appeared to depend on the base-sensitivity of the Michael acceptor, but the method is applicable across a broad range of cyclic α,β-unsaturated ketone esters. Functional group transformations can be undertaken following pyrrole synthesis to increase the diversity of cycloalkanopyrroles accessible by this method. One pyrrole thus made is a diester of a conformationally-constrained analogue of porphobilinogen, the precursor of the natural tetrapyrroles.