1358917-13-1Relevant articles and documents
Rhodium-catalyzed 1,3-acyloxy migration and subsequent intramolecular [4+2] cycloaddition of vinylallene and unactivated alkyne
Huang, Suyu,Li, Xiaoxun,Lin, Claire L.,Guzei, Ilia A.,Tang, Weiping
supporting information; experimental part, p. 2204 - 2206 (2012/04/23)
A Rh-catalyzed 1,3-acyloxy migration of propargyl ester followed by intramolecular [4+2] cycloaddition of vinylallene and unactivated alkyne was developed. This tandem reaction provides access to bicyclic compounds containing a highly functionalized isotoluene or cyclohexenone structural motif, while only aromatic compounds were observed in related transition metal-catalyzed cycloadditions.