1361456-15-6

Basic information

• Product Name: C₆H₅-C{NH(CH₂)2SMe}=NC₆H₅
• Synonyms: C₆H₅-C{NH(CH₂)2SMe}=NC₆H₅
• CAS NO: 1361456-15-6
• Molecular Weight: 270.398
• Mol File: 1361456-15-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₆H₅-C{NH(CH₂)2SMe}=NC₆H₅(CAS DataBase Reference)
• NIST Chemistry Reference: C₆H₅-C{NH(CH₂)2SMe}=NC₆H₅(1361456-15-6)
• EPA Substance Registry System: C₆H₅-C{NH(CH₂)2SMe}=NC₆H₅(1361456-15-6)

Safety Data

• Hazardous Substances Data: 1361456-15-6(Hazardous Substances Data)

Upstream product

• 6950-53-4 2‐(methylsulfanyl)ethan‐1‐amine hydrochloride 
• 4903-36-0 N-phenyl-benzimidoyl chloride 

Downstream Products

• 1361456-27-0 Pd(C₆H₄NHC(C₆H₅)NCH₂CH₂SCH₃)Cl 

Relevant articles and documents

Palladacycles bearing tridentate CNS-type benzamidinate ligands as catalysts for cross-coupling reactions

Three pendant benzamidines, [Ph-C(NC6H5)-{NH(E)}] [E = -(CH2)2SMe (1); -(CH2)2S tBu (2); -o-C6H4SMe (3)], are described. Reactions of 1, 2 or 3 with one molar equivalent of Pd(OAc)2 in CH2Cl2 give the palladacyclic complexes, [Ph-C{-NH(η1-C6H4)}{N(E)}]Pd(OAc) [E = -(CH2)2SMe (4); -(CH2)2S tBu (5); -o-C6H4SMe (6)], as mononuclear palladium complexes respectively. A minor product described as 5′, {[Ph-C{-N(C6H5)}{-N(CH2)2S tBu}]Pd(OAc)}2, was isolated as benzamidinate-bridged dinuclear palladium complex upon recrystallizing from Et2O/hexane solution. Treatment of 1, 2 or 3 with one molar equivalent of PdCl2 in the presence of NEt3 in CH2Cl2 gives the palladacyclic complexes, [Ph-C{-NH(η1-C6H 4)}{N(E)}]PdCl [E = -(CH2)2SMe (7); -(CH 2)2StBu (8); -o-C6H4SMe (9)], as mononuclear palladium complexes respectively. The crystal and molecular structures are reported for compounds 5, 5′ and 6-8. The application of these palladacyclic complexes to the Suzuki and Heck coupling reactions was examined.