136787-49-0

Basic information

• Product Name: Silane, (1,1-dimethylethyl)diphenyl(2-propenyloxy)-
• CAS NO: 136787-49-0
• Molecular Formula: C19H24OSi
• Molecular Weight: 296.484
• Mol File: 136787-49-0.mol
• Article Data: 27

Chemical Properties

• CAS DataBase Reference: Silane, (1,1-dimethylethyl)diphenyl(2-propenyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,1-dimethylethyl)diphenyl(2-propenyloxy)-(136787-49-0)
• EPA Substance Registry System: Silane, (1,1-dimethylethyl)diphenyl(2-propenyloxy)-(136787-49-0)

Safety Data

• Hazardous Substances Data: 136787-49-0(Hazardous Substances Data)

Upstream product

• 88159-06-2 tert-butyl(diphenyl)(2-propynyloxy)silane 
• 107-18-6 allyl alcohol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 186900-91-4 (3aS,3bS,5S,7R,7aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-7-phenylselanylmethyl-hexahydro-1,3,6-trioxa-6a-aza-cyclopenta[a]pentalene 
• 355117-89-4 3-(tert-butyldiphenylsilyloxy)-1,2-dibromopropane 
• 374934-05-1 5-(tert-butyldiphenylsilanyloxy)-2-fluoro-4-iodopentanoic acid ethyl ester 
• 376652-70-9 toluene-4-sulfonic acid 6-(tert-butyl-diphenyl-silanyloxy)-3-methylene-hex-4-enyl ester 
• 292616-85-4 pent-4-ynoic acid 2-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-benzyl ester 
• 95514-04-8 (R)-3-(tert-butyldiphenylsilyloxy)-2-methylpropan-1-ol 
• 95514-04-8 (S)-3-(tert-butyldiphenylsilyloxy)-2-methylpropan-1-ol 
• 868-24-6 diethyl 2,3-difluorosuccinate 
• 1062504-98-6 tert-butyl (3-(diphenylsilyl)propoxy)(diphenyl)silane 
• 1352816-01-3 C₃₆H₄₈O₇Si 
• 1352816-02-4 C₃₂H₄₆O₆Si 
• 125111-27-5 (R)-3-((tert-butyldiphenylsilyl)oxy)propane-1,2-diol 
• 161469-43-8 (S)-3-((tert-butyldiphenylsilyl)oxy)propane-1,2-diol 
• 118171-02-1 1-(tert-butyldiphenylsilyloxy)-2-propanone 

Relevant articles and documents

An efficient and general method for the synthesis of α,ω- difunctional reduced polypropionates by Zr-catalyzed asymmetric carboalumination: Synthesis of the scyphostatin side chain

A decrease in the number of linear synthetic steps and an increase in efficiency have been realized in the synthesis of the side chain of scyphostatin. An efficient and selective synthesis of α,ω- difunctional reduced polypropionates from methyl 3-hydroxy-2-methylpropionate through the use of a Zr-catalyzed asymmetric carboalumination has been developed (see scheme, TBS = tert-butyldimethylsilyl).

Carbohydrate/DBU Cocatalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope

A mechanistic investigation of the carbohydrate/DBU cocatalyzed enantioselective diboration of alkenes is presented. These studies provide an understanding of the origin of stereoselectivity and also reveal a strategy for enhancing reactivity and broadening the substrate scope.

COMPOUNDS FOR USE IN THE TREATMENT OF INFECTIOUS DISEASES

The present invention relates to compounds of formula (I), wherein R1, R2, R3, R4, R5 and R6 are as described herein, and their prodrugs or pharmaceutically acceptable salt, enantiomer or diastereomer thereof, and compositions including the compounds and methods of using the compounds.