137066-22-9

Basic information

• Product Name: 4-cyanobenzenediazonium 4-methylbenzenesulfonate
• Synonyms: 4-cyanobenzenediazonium 4-methylbenzenesulfonate
• CAS NO: 137066-22-9
• Molecular Weight: 301.326
• Mol File: 137066-22-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4-cyanobenzenediazonium 4-methylbenzenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-cyanobenzenediazonium 4-methylbenzenesulfonate(137066-22-9)
• EPA Substance Registry System: 4-cyanobenzenediazonium 4-methylbenzenesulfonate(137066-22-9)

Safety Data

• Hazardous Substances Data: 137066-22-9(Hazardous Substances Data)

Upstream product

• 104-15-4 toluene-4-sulfonic acid 
• 873-74-5 4-Aminobenzonitrile 

Downstream Products

• 3058-39-7 4-iodobenzonitrile 
• 67472-79-1 methyl 3-(4-cyanophenyl)propenoate 
• 623-00-7 4-bromobenzenecarbonitrile 

Relevant articles and documents

Synthesis of Symmetric Binuclear 5,6-Dihydro-1,2,4,5-tetrazinium Perchlorates

Abstract: A series of 3,3′-(1,4-phenylene)bis(1-4-R-phenyl)-5-phenyl-5,6-dihydro-1,2,4,5-tetrazinium) perchlorates (R = H, Me, Cl, OMe, CN, NO2) were obtained as a result of a three-stage synthesis from terephthalic aldehyde. The synthesis of tetrazinium salts was carried out by reaction of the corresponding formazans with formalin in the presence of perchloric acid in dioxane. Formazans and tetrazinium perchlorates were isolated in individual state and characterized by elemental analysis, IR, UV, 1H, and 13C NMR spectroscopy data. The process of electrochemical reduction of tetrazinium perchlorates was studied using the method of cyclic voltammetry (CV). It has been shown that these compounds are perspective precursors of symmetric biradical systems based on verdazyl radicals.

Unusually stable, versatile, and pure arenediazonium tosylates: Their preparation, structures, and synthetic applicability

(Graph Presented) A new, simple, and effective method for the diazotization of a wide range of arylamines has been developed by using a polymer-supported diazotization agent in the presence of p-toluenesulfonic acid. Various pure arenediazonium tosylates with unusual stabilities can be easily prepared by this method. As a result, these salts are useful and versatile substrates for subsequent transformations, such as halogenation and Heck-type reactions. The unusual stabilities of arenediazonium tosylates are also preliminarily discussed with their X-ray structures.

Electro-optical materials and light modulator devices containing same

Azo-type optically active compounds and polymers are provided based on compounds of the general structure wherein aryl substituents are introduced which hinder or prohibit rotation around the single bonds of the --N=-- central moiety (as well as around certain other single bonds), to provide "planarized" structures having improved optically active properties, especially electro-optically active properties. These compounds and polymers find use in optically active waveguides.