1375478-70-8

Basic information

• Product Name: tert-butyl(hept-5-yn-1-yloxy)diphenylsilane
• Synonyms: tert-butyl(hept-5-yn-1-yloxy)diphenylsilane
• CAS NO: 1375478-70-8
• Molecular Weight: 350.576
• Mol File: 1375478-70-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-butyl(hept-5-yn-1-yloxy)diphenylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl(hept-5-yn-1-yloxy)diphenylsilane(1375478-70-8)
• EPA Substance Registry System: tert-butyl(hept-5-yn-1-yloxy)diphenylsilane(1375478-70-8)

Safety Data

• Hazardous Substances Data: 1375478-70-8(Hazardous Substances Data)

Upstream product

• 128217-23-2 1-(tert-butyldiphenylsilyloxy)-5-hexyne 
• 74-88-4 methyl iodide 
• 928-90-5 5-hexyl-1-ol 

Downstream Products

• 1375478-71-9 (E)-tert-butyl((6-iodohept-5-en-1-yl)oxy)diphenylsilane 
• 1375478-79-7 methyl (1R,2S,5R,6S)-5-((tert-butyldimethylsilyl)oxy)-2-(4-((tert-butyldiphenylsilyl)oxy)butyl)-6-isopropyl-3-methylcyclohex-3-enecarboxylate 
• 1375478-78-6 C₃₇H₅₈O₄Si₂ 
• 1375478-80-0 methyl (1R,2S,5R,6S)-5-hydroxy-2-(4-hydroxybutyl)-6-isopropyl-3-methylcyclohex-3-enecarboxylate 
• 1375478-81-1 methyl (1R,2S,6S)-6-isopropyl-3-methyl-5-oxo-2-(4-oxobutyl)cyclohex-3-enecarboxylate 
• 1375478-86-6 C₃₄H₄₉NO₄Si 
• 2115-91-5 dendrobine 

Relevant articles and documents

Total synthesis of (-)-dendrobine

Cascading to alkaloids: An 18-step total synthesis of (-)-dendrobine is based on a reaction cascade with a key amine group (see scheme, Bn=benzyl). The amine is the initiator of the cascade and provides an efficient method for installing the stereocenters at C11 and C3. The overall transformation occurs stereoselectively only when the conversion is carried out without the isolation of intermediates. Copyright