1380419-28-2Relevant articles and documents
Palladium-catalyzed alkylation of 1,4-dienes by Ci-H activation
Trost, Barry M.,Hansmann, Max M.,Thaisrivongs, David A.
supporting information; experimental part, p. 4950 - 4953 (2012/06/16)
Activated: The title reaction proceeds with a broad range of nucleophiles and variously substituted 1,4-dienes under mild conditions, and provides direct access to the corresponding 1,3-diene-containing products with high regio- and stereocontrol (see scheme; 2,6-DMBQ=2,6-dimethylbenzoquinone, EWG=electron-withdrawing group). This is the first catalytic allylic Ci-H alkylation that proceeds in the absence of sulfoxide ligands. Copyright
