13814-75-0 Usage
Description
Molybdenum (VI) Tetrachloride Oxide, also known as Molybdenum Oxotetrachloride, is a green, volatile powder that is sensitive to moisture. It is a compound with the chemical formula MoOCl4 and is known for its unique chemical properties and various applications across different industries.
Uses
Used in Polymer Industry:
Molybdenum (VI) Tetrachloride Oxide is used as a catalyst for the living polymerization of various acetylenes. This application is significant because it allows for the controlled synthesis of polymers with specific properties, which can be tailored for various end-use applications.
Used in Pharmaceutical Industry:
Molybdenum (VI) Tetrachloride Oxide serves as an oxidant in the aromatization of various Hantzsch-1,4-dihydropyridines. This process is crucial in the synthesis of certain pharmaceutical compounds, as it helps to convert the dihydropyridine intermediates into their aromatic forms, which possess the desired biological activities.
Used in Catalyst Preparation:
Molybdenum (VI) Tetrachloride Oxide is used as a molybdenum (Mo) precursor to prepare nafion-Mo composite material. This composite material acts as a catalyst for the preparation of nitrones by reacting primary amines with aldehydes. Nitrones are important intermediates in the synthesis of various organic compounds, including pharmaceuticals and agrochemicals.
Check Digit Verification of cas no
The CAS Registry Mumber 13814-75-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,8,1 and 4 respectively; the second part has 2 digits, 7 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 13814-75:
(7*1)+(6*3)+(5*8)+(4*1)+(3*4)+(2*7)+(1*5)=100
100 % 10 = 0
So 13814-75-0 is a valid CAS Registry Number.
InChI:InChI=1/4ClH.Mo.O/h4*1H;;/q;;;;+4;/p-4/rCl4MoO/c1-5(2,3,4)6
13814-75-0Relevant articles and documents
Synthesis and IR spectroscopic study of molecular complexes of molybdenum oxotetrachloride with azomethines
Abramenko
, p. 819 - 823 (2001)
Molecular complexes of MoOCl4 with benzal- and salicylalanilines were synthesized, and their IR spectra were investigated. The complexes have octahedral structure. Salicylalaniline and its derivatives were suggested to be coordinated by the cen
Reactions of MoOCl4 and MoO2Cl2 with heterocyclic thioamides
Rani, Deepika,Singh, Gursharan,Sharma, Seema
, p. 459 - 466 (2021/05/19)
MoOCl4/MoO2Cl2 were reacted with 2-mercaptopyridine (IUPAC: pyridine-2-thiol)/4phenylimidazole-2-thiol (IUPAC: 4-phenyl-1,3-dihydroimidazole-2-thione)/6-mercaptopurine (IUPAC: 1,7-dihydro-purine-6-thione) in acetonitrile m
Spectroscopic Studies on Matrix-isolated Molybdenum Pentachloride
Brisdon, Alan K.,Graham, John T.,Hope, Eric G.,Jenkins, Delyth M.,Levason, William,Ogden, J. Steven
, p. 1529 - 1532 (2007/10/02)
Matrix-isolation studies have been carried out on molybdenum petnachloride.In a nitrogen-matrix, prominent i.r. bands are observed at ca. 473 and 408 cm-1, which on the basis of isotope studies are assigned as the A1 (axial and E Mo-Cl stretching modes of monomeric MoCl5 (C4v).Argon matrices yielded essentially the same spectroscopic features.Corresponding u.v.-visible spectra were obtained and assigned on the basis of a square-pyramidal geometry.Attempts to prepare and characterise MoCl6 were unsuccessful.