Molybdenum(VI) tetrachloride oxide

Base Information

• Chemical Name: Molybdenum(VI) tetrachloride oxide
• CAS No.: 13814-75-0
• Molecular Formula: Cl₄MoO
• Molecular Weight: 253.751
• Hs Code.: 2827499090
• European Community (EC) Number: 628-149-2
• DSSTox Substance ID: DTXSID501298196
• Wikipedia: Molybdenum_oxytetrachloride
• Mol file: 13814-75-0.mol

Synonyms:Molybdenum(VI) tetrachloride oxide;13814-75-0;MOLYBDENUM (VI) TETRACHLORIDE OXIDE;oxomolybdenum;tetrahydrochloride;tetrachlorooxomolybdenum;O=MoCl4;MoCl4O;MoOCl4;MFCD00014222;[MoCl4O];tetrachloridooxidomolybdenum;oxomolybdenum(VI) chloride;tetrachloridooxidomolybdenum(VI);CHEBI:30698;DTXSID501298196;Molybdenum chloride oxide (MoCl4O);Molybdenum(VI) tetrachloride oxide, 97%;CS-0111850

Chemical Property of Molybdenum(VI) tetrachloride oxide

Chemical Property:

• Melting Point: 100-101°C
• PSA: 17.07000
• LogP: 2.63920
• Storage Temp.: 2-8°C
• Sensitive.: air sensitive, moisture sensitiv
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 259.804079
• Heavy Atom Count: 6
• Complexity: 7.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

Molybdenum(VI) tetrachloride oxide, min. 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,C
• Statements: 36/37/38-34
• Safety Statements: 26-37/39-45-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: O=[Mo].Cl.Cl.Cl.Cl
• Uses: Molybdenum(VI) tetrachloride oxide can be used:To prepare a binary metal catalyst (MoOCl4-n-BuLi) for the living polymerization of various acetylenes.As an oxidant in the aromatization of various Hantzsch-1,4-dihydropyridines.As a molybdenum (Mo) precursor to prepare nafion-Mo composite material, which is used as a catalyst for the preparation of nitrones by reacting primary amines with aldehydes.

Technology Process of Molybdenum(VI) tetrachloride oxide

There total 18 articles about Molybdenum(VI) tetrachloride oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

molybdenum(VI) oxide → molybdenum(VI) tetrachloride oxide (55171-05-6,13814-75-0) + dioxomolybdenum(VI) dichloride (13637-68-8)

Guidance literature:

With chlorine; in presence of C; above 600°C (>18 l/h); C:MoO3 = 1:1;

Reference yield:

copper(II) molybdate → molybdenum(VI) tetrachloride oxide (55171-05-6,13814-75-0) + dioxomolybdenum(VI) dichloride (13637-68-8)

Guidance literature:

With tetrachloromethane; In not given; byproducts: copper chloride;

Reference yield:

molybdenum(V) chloride (10241-05-1) + molybdenum(VI) oxide → molybdenum(VI) tetrachloride oxide (55171-05-6,13814-75-0) + molybdenum oxide trichloride + dioxomolybdenum(VI) dichloride (13637-68-8)

Guidance literature:

In neat (no solvent); 85-100°C, closed vessel;

upstream raw materials:

thionyl chloride

aluminium trichloride

disulfur dichloride

molybdenum(V) chloride

Downstream raw materials:

chloro-trimethyl-silane

Mo(O)(S)Cl₂

MoCl₃(N(2,6-diisopropylphenyl))(N-2',6'-diisopropylphenyl-2,5-dimethyl benzamide)2

Refernces

• 1、 Taylor, John C.,Waugh, A. Bruce. "Crystal and Molecular Structure of Molybdenum Tetrachloride Oxide by Neutron and X-Ray Diffraction". . p. 2006 - 2009. Retrieved 1980.
• 2、 Safonov,Korshunov. "The MoOCl4-TeCl4 System". . p. 1427 - 1428. Retrieved 2008/10/08.