1394206-65-5Relevant articles and documents
α-aminoxylation of ketones and β-chloro-α-aminoxylation of enones with tempo and chlorocatecholborane
Li, Yi,Pouliot, Martin,Vogler, Thomas,Renaud, Philippe,Studer, Armido
supporting information, p. 4474 - 4477 (2012/10/30)
Oxidation of various cyclic and acyclic ketones under mild conditions with chlorocatecholborane, a bulky pyridine base, and TEMPO to the corresponding α-aminoxylated products in good to excellent yields (52-99%) is described. For enones as substrates, products of a β-chloro-α-aminoxylation are obtained (70-89%).