1395044-62-8Relevant articles and documents
Pyran-Bridged Indacenodithiophene as a Building Block for Constructing Efficient A–D–A-Type Nonfullerene Acceptors for Polymer Solar Cells
Wen, Shuguang,Wu, Yao,Wang, Yingying,Li, Yi,Liu, Ling,Jiang, Huanxiang,Liu, Zhitian,Yang, Renqiang
, p. 360 - 366 (2018)
In recent years, nonfullerene acceptors have attracted much attention, owing to their great potential for use in high-performance polymer solar cells.The ladder-type building block, pyran-bridged indacenodithiophene (PDT), was used for constructing A–D–A nonfullerene acceptors through introduction of oxygen atoms into an indacenodithiophene (IDT) unit. The synthesis of PDT is accomplished by a BBr3-mediated tandem cyclization–deprotection reaction to construct the pyran ring. Hence, molecular acceptor PTIC was synthesized and used in a polymer solar cell device. Compared to the IDT-based acceptor, PTIC exhibits higher HOMO levels and wider optical band gap at 550–800 nm. Devices fabricated with poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b′]dithiophene)-co-(1,3-di(5-thiophene-2-yl)-5,7-bis(2-ethylhexyl)-benzo[1,2-c:4,5-c′]dithiophene-4,8-dione)] (PBDB-T):PTIC as the active layer give a power conversion efficiency (PCE) of 7.66 %.
Partially ladder-type molecule-based donor-acceptor conjugated oligomer: Synthesis and properties
Poduval, Mithrabinda K. K.,Hahn, So-Jung,Kim, Tae-Hyun
scheme or table, p. 2040 - 2042 (2012/08/08)
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