139979-24-1Relevant articles and documents
Communication of electronic information over nanometer distances with supramolecular transduction. An experimental and density functional investigation
Deans, Robert,Cuello, Alejandro O.,Galow, Trent H.,Ober, Matthias,Rotello, Vincent M.
, p. 1309 - 1313 (2007/10/03)
We have synthesized a family of conjugated diaminotriazine-functionalized receptors. Variation of distal functionality modulated the affinity of these receptors for flavin, demonstrating efficient electronic communication over a distance of 11 A. The origin of this communication was explored using DFT methodology. These calculations demonstrate that modulation of recognition in these systems is derived from a complex push-pull type mechanism.