14057-91-1

Basic information

• Product Name: Tetrakis(acetonitrile)copper(I) Perchlorate
• Synonyms: Tetrakis(acetonitrile)copper(I) Perchlorate
• CAS NO: 14057-91-1
• Molecular Formula: C8H16ClCuN4O4
• Molecular Weight: 327.207
• Mol File: 14057-91-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Tetrakis(acetonitrile)copper(I) Perchlorate(CAS DataBase Reference)
• NIST Chemistry Reference: Tetrakis(acetonitrile)copper(I) Perchlorate(14057-91-1)
• EPA Substance Registry System: Tetrakis(acetonitrile)copper(I) Perchlorate(14057-91-1)

Safety Data

• Hazardous Substances Data: 14057-91-1(Hazardous Substances Data)

Upstream product

• 75-05-8 acetonitrile 
• 1428241-63-7 2,4-ditert-butyl-6-{4-[2-(6,8-ditert-butyl-4H-benzo[e][1,3]oxazin-3-yl)-ethyl]piperazin-1-ylmethyl}phenol 

Downstream Products

• 125841-44-3 Cu(((C₆H₅)C₅H₃NS(CHN))2(CH₂)4)⁽¹⁺⁾*ClO₄^(1-) = {Cu(C₂₈H₂₆N₄S₂)}(ClO₄) 
• 125841-42-1 Cu(((C₆H₅)C₅H₃NS(CHN))2(CH₂)3)⁽¹⁺⁾*ClO₄^(1-) = {Cu(C₂₇H₂₄N₄S₂)}(ClO₄) 
• 921622-56-2 [Cu((2,4-dimethylphenyl)-pyridin-2-ylmethylene-amine)2]ClO₄ 
• 921622-53-9 [Cu((2,3-dimethylphenyl)-pyridin-2-ylmethylene-amine)2]ClO₄ 
• 921622-58-4 [Cu((2,5-dimethylphenyl)-pyridin-2-ylmethylene-amine)2]ClO₄ 
• 886971-80-8 [(1-benzyl-[3-(2'-pyridyl)]pyrazole)Cu(MeCN)2][ClO₄] 
• 871031-04-8 [Cu(N,N-bis(6-methylpyridin-2-ylmethyl)benzylamine)(CH₃CN)]ClO₄ 
• 216142-54-0 Cu(P(C₆H₅)3)(C₁₃H₁₃N₅)⁽¹⁺⁾*ClO₄^(1-) = [Cu(P(C₆H₅)3)(C₁₃H₁₃N₅)]ClO₄ 
• 498584-33-1 [Cu(1,2-bis(diphenylphosphino)ethane)(1,10-phenanthroline)]ClO₄ 
• 695184-49-7 Cu(I) bis(2,4,6-triphenylphosphinine) perchlorate 
• 207455-33-2 2,2'-bipyridine copper(II) flavonolate perchlorate 
• 851428-11-0 Cu(CH₃CN)2(2,6-bis(N-benzyl-N-diphenylphosphinomethylamino)pyridine)ClO₄ 

Relevant articles and documents

Solvent dependent ligand transformation in a dinuclear copper(ii) complex of a compartmental Mannich-base ligand: Synthesis, characterization, bio-relevant catalytic promiscuity and magnetic study

An "end-off" pentadentate compartmental ligand HL has been synthesized by Mannich base condensation using p-cresol and 2-benzyl amino ethanol and structurally characterized. A dinuclear copper(ii) complex, namely [Cu2(L)(μ-OH)(H2O)(C

Formation of a Cu(II)-phenoxyl radical complex from a Cu(II)-phenolate complex: A new model for galactose oxidase

A new N3O type tetradentate ligand (HL) [2,4-di-tert-butyl-6- ((4-(2-(6,8-di-tert-butyl-2H-benzo[e][1,3]oxazin-3(4H)-yl)ethyl)piperazin-1-yl) methyl)phenol] and its complex [CuL(CH3OH)]ClO4(CH 3OH) have been synthesised. The complex has been crystallographically and spectroscopically characterised. It has been noticed that in the presence of acetonitrile the Cu(II) centers in the complex undergo reduction with a concomitant oxidation of the ligand. EPR and UV-Vis spectroscopic studies of the complex in acetonitrile indicate that this disproportionation proceeds via the formation of a Cu(II)-phenoxyl intermediate. The Cu(II)-phenoxyl complex is found to be stable in methanol in the presence of base. The oxidised products of the ligand are isolated and characterized. The paramagnetic centers in the Cu(II)-phenoxyl complexes were found to be weakly ferromagnetically coupled.

Reduction of copper(II) complexes of tripodal ligands by nitric oxide and trinitrosation of the ligands

The copper(II) centers in two copper(II) complexes of tripodal amine ligands, in acetonitrile solvent, upon exposure to nitric oxide have been found to produce a thermally unstable [CuII-NO] intermediate followed by the reduction of copper(II)