140866-59-7Relevant articles and documents
Synthesis and photochromism of some mono and bis (thienyl) substituted oxathiine 2,2-dioxides
Aiken, Stuart,Gabbutt, Christopher D.,Heron, B. Mark,Rice, Craig R.,Zonidis, Dimitrios
, p. 9578 - 9584 (2019)
1,2-Oxathiine 2,2-dioxides have been obtained from their respective 3,4-dihydro-4-dimethylamino precursors, for the first time, by a mild Cope elimination of the 4-dimethylamino function. The application of the 1,2-oxathiine 2,2-dioxide scaffold in materi
A convenient alternative route to β-aminoketones
San Martin,De Marigorta,Dominguez
, p. 2255 - 2264 (2007/10/02)
Enaminones has been prepared and submitted to conjugate reduction with LAH and the system Al2O3/R2NH to give β-aminoketones. The latter tandem amination system has also been applied in the Mannich reaction, improving the synthesis of several new diaryl β-aminoketones. Besides, the sequential use of DMFDMA and LAH-CuI on deoxybenzoins furnishes a new route for the synthesis of enones.