1418096-13-5

Basic information

• Product Name: (5R,6S)-6-(methoxymethoxy)-5-methyl-1-vinylcyclohex-1-ene
• Synonyms: (5R,6S)-6-(methoxymethoxy)-5-methyl-1-vinylcyclohex-1-ene
• CAS NO: 1418096-13-5
• Molecular Weight: 182.263
• Mol File: 1418096-13-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (5R,6S)-6-(methoxymethoxy)-5-methyl-1-vinylcyclohex-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (5R,6S)-6-(methoxymethoxy)-5-methyl-1-vinylcyclohex-1-ene(1418096-13-5)
• EPA Substance Registry System: (5R,6S)-6-(methoxymethoxy)-5-methyl-1-vinylcyclohex-1-ene(1418096-13-5)

Safety Data

• Hazardous Substances Data: 1418096-13-5(Hazardous Substances Data)

Upstream product

• 5524-05-0 (2R,5R)-5-isopropenyl-2-methylcyclohexanone 
• 1418096-12-4 (1S,6R)-6-methyl-2-vinylcyclohex-2-enol 
• 107-30-2 chloromethyl methyl ether 
• 1418096-11-3 (R)-6-methyl-2-vinylcyclohex-2-enone 
• 1418096-10-2 (R)-2-iodo-6-methylcyclohex-2-enone 
• 62392-84-1 (+)-(R)-6-methylcyclohex-2-en-1-one 

Downstream Products

• 96695-57-7 fujianmycin A 

Relevant articles and documents

Total syntheses of rubiginone A2, C2, and fujianmycin A

The total syntheses of rubiginone A2, C2 and fujianmycin A are described. The synthesis involves Diels-Alder/aromatization and photo chemical reactions as key steps to construct the tetracyclic frame of benz[a]anthraquinone skeleton.

Determining the absolute configuration of benzopyrenomycin by optical rotation, electronic circular dichroism, and population analysis of different conformations via DFT methods and experiments

In this work, we have studied the absolute configuration of benzopyrenomycin using different density functional theory (DFT) methods, such as optical rotation (OR), electronic circular dichroism (ECD), and conformation distribution analysis for three kinds of Mosher esters at different levels, e.g., B3LYP/6-31G(d), B3LYP/6-311+G(d), and B3LYP/6-311++G(2d,p) in the gas phase and in solution, respectively. Careful investigations for different chiral Mosher esters using DFT theory exhibited the application conditions for certain chiral molecules in absolute configuration determination. Benzopyrenomycin possesses a unique benzo[a]pyrene-type skeleton and shows strong cytotoxicity against various tumor-cell lines.