142819-91-8

Basic information

• Product Name: 1-Propanone, 2-diazo-1-[2-(phenylmethoxy)phenyl]-
• CAS NO: 142819-91-8
• Molecular Formula: C16H14N2O2
• Molecular Weight: 266.299
• Mol File: 142819-91-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 2-diazo-1-[2-(phenylmethoxy)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 2-diazo-1-[2-(phenylmethoxy)phenyl]-(142819-91-8)
• EPA Substance Registry System: 1-Propanone, 2-diazo-1-[2-(phenylmethoxy)phenyl]-(142819-91-8)

Safety Data

• Hazardous Substances Data: 142819-91-8(Hazardous Substances Data)

Upstream product

• 1117-96-0 Diazoethan 
• 4349-62-6 2-benzyloxybenzoyl chloride 
• 69-72-7 salicylic acid 
• 14389-86-7 2-benzyloxybenzoic acid 
• 14389-87-8 benzyl 2-(benzyloxy)benzoate 

Downstream Products

• 15334-22-2 2,3-trans-2,3-dihydro-3-methyl-2-phenyl-4H-1-benzopyran-4-one 

Relevant articles and documents

Chemoselectivity and stereoselectivity of cyclisation of α-diazocarbonyls leading to oxygen and sulfur heterocycles catalysed by chiral rhodium copper catalysts

Good levels of enantioselectivity have been achieved in intramiolecular C-H insertion reactions of α-diazocarbonyl compounds leading to six-membered oxygen heterocycles (chromanones) through the use of chiral rhodium(II) carboxylates as catalysts.Competition between C-H insertion and sigmatropic rearrangement, the latter leading to five-membered oxygen heterocycles (furanones), was observed with precursors containing a proximal O-allyl side chain.Whereas rhodium carboxylates produced C-H insertion products predominantly, a copper catalyst produced sigmatropic rearrangement products exclusively.A precursor with S-allyl side chain exhibited cyclisation via sigmatropic rearrangement with both copper and rhodium catalyst.