14297-81-5

Basic information

• Product Name: Chrysanthemoyl chloride
• Synonyms: 2,2-dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarbonyl chloride;chrysanthemoyl chloride;CHRYSANOYL CHLORIDE;(±)cis，trans-2，2-dimethyl-3-(2-methyl-1-propenyl cyclopropane carbonyl chloride);(1R-cis)-2,2-Dimethyl-3-(2-methylprop-1-enyl) cyclopropanecarbonyl chloride
• CAS NO: 14297-81-5
• Molecular Formula: C₁₀H₁₅ClO
• Molecular Weight: 186.68
• EINECS: 238-229-5
• Mol File: 14297-81-5.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 206°C
• Flash Point: 100°C
• Appearance: /
• Density: 1.098
• Vapor Pressure: 0.243mmHg at 25°C
• Refractive Index: 1.533
• CAS DataBase Reference: Chrysanthemoyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: Chrysanthemoyl chloride(14297-81-5)
• EPA Substance Registry System: Chrysanthemoyl chloride(14297-81-5)

Safety Data

• Hazardous Substances Data: 14297-81-5(Hazardous Substances Data)

Usage

General Description

Chrysanthemoyl chloride is a chemical compound with the molecular formula C10H11ClO2. It is a derivative of chrysanthemic acid, which is found in certain species of chrysanthemum flowers. Chrysanthemoyl chloride is used as a raw material in the synthesis of pyrethroid insecticides, which are commonly used in agricultural applications to control pests. It is also used in the production of pharmaceuticals and other organic compounds. Chrysanthemoyl chloride is a colorless liquid with a pungent odor, and it is highly reactive, making it important to handle it with caution.

InChI:InChI=1/C10H15ClO/c1-6(2)5-7-8(9(11)12)10(7,3)4/h5,7-8H,1-4H3

Upstream product

• 10453-89-1 chrysanthemumic acid 
• 97-41-6 ethyl 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate 
• 2935-23-1 cis-Chrysanthemic acid 
• 3815-09-6 1-bromo-2,2-dimethylcyclopropane 
• 32264-50-9 1,1-dibromo-2,2-dimethylcyclopropane 
• 3907-06-0 3,3-Dimethylcyclopropen 

Downstream Products

• 584-79-2 (+/-)(1Ξ)-cis-chrysanthemumic acid-((Ξ)-3-allyl-2-methyl-4-oxo-cyclopent-2-enyl ester) 
• 97-12-1 (+/-)(1Ξ)-cis-chrysanthemumic acid-((Ξ)-3-but-2c-enyl-2-methyl-4-oxo-cyclopent-2-enyl ester) 
• 2861-25-8 cis-chrysanthemyl alcohol 
• 2756-54-9 (+/-)-cis-chrysanthemumic acid-(4-chloro-phenyl ester) 
• 80814-57-9 chrysanthemumic acid diethylamide 
• 5458-67-3 Chrysanthemumsaeure-<1-methyl-propylester> 
• 63416-87-5 2,2-dimethyl-3-(1-isobutenyl)-cyclopropanecarboxylic acid 3-(2,2-dichlorovinyloxy)-α-cyanobenzyl ester 
• 1390617-19-2 C₂₀H₂₅ClO₄ 
• 1390617-12-5 C₂₀H₂₆O₄ 
• 34905-22-1 (±)-cis- and (±)-trans-[5-(phenoxymethyl)furan-2-yl]methyl-2,2-dimethyl-3-(2-methylprop-1-en-1-yl)-cyclopropane-1-carboxylate 
• 271241-14-6 2,3,5,6-tetrafluoro-4-(methoxymethyl)benzyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate 
• 10453-89-1 chrysanthemumic acid 
• 23031-38-1 furamethrin 
• 454-25-1 (+/-)-cis-Homochrysanthemsaeure 

Relevant articles and documents

A New Synthesis of cis-Chrysanthemic Acid

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Synthesis and characterization of chrysanthemic acid esters

A short and convenient synthesis for a series of novel chrysanthemic acid esters from aldehyde and chrysanthemic acid is reported.

BETULIN DERIVED COMPOUNDS AS ANTI-FEEDANTS FOR PLANT PESTS

The invention relates to compounds derived from betulin, and to the use thereof in plant pest control, particularly as antifeedants for butterfly larvae, beetles and snails. Further, the invention relates to novel betulin derivatives and methods for the production thereof either directly from betulin, or via intermediates derived therefrom.

Parallel synthesis and herbicidal activity of pyrethroid library

A pyridine-containing pyrethroid library of 255 compounds was conveniently constructed using parallel synthesis. The library was screened by high through-put screening (HTS), and further study was focused on the compounds with initial bioactivities. The results suggest that some compounds could be potential herbicides.