14309-88-7Relevant articles and documents
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Schlatter
, p. 2722 (1942)
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An Aluminum(III)-Catalyzed Thioamide-Aldehyde-Styrene Condensation: Direct Synthesis of Allylic Thioamide Derivatives
Xu, Bin,Zhong, Xue,Wang, Xi-Cun,Quan, Zheng-Jun
, p. 2237 - 2240 (2016)
An aluminum(III) triflate catalyzed three-component synthesis of allylic thioamide derivatives by condensation of a thioamide, paraformaldehyde and a styrene is reported.
An Efficient Heterobimetallic Lanthanide Alkoxide Catalyst for Transamidation of Amides under Solvent-Free Conditions
Sheng, Hongting,Zeng, Ruijie,Wang, Wenjuan,Luo, Shuwen,Feng, Yan,Liu, Jing,Chen, Weijian,Zhu, Manzhou,Guo, Qingxiang
, p. 302 - 313 (2017/02/05)
A practical heterobimetallic lanthanide-catalyzed transamidation of primary, secondary and tertiary amides with aliphatic and aromatic amines has been developed. The methodology was also applied to the weakly reactive thioamides to demonstrate its versatility and wide substrate scope. The heterobimetallic lanthanide catalysts showed high catalytic activity and a wide scope of substrates with good to excellent yields under solvent-free conditions. Efficient activation of the transamidation can be realized by the above complexes acting as cooperative acid–base bifunctional catalysts, which are proposed to be responsible for the higher reactivity in comparison with simple monometallic catalysts. (Figure presented.).
Selective thioacylation of amines in water: A convenient preparation of secondary thioamides and thiazolines
Pathak, Uma,Bhattacharyya, Shubhankar,Mathur, Sweta
, p. 4484 - 4488 (2015/02/19)
Primary thioamides have been utilised directly in water, without any derivatisation, to selectively thioacylate primary amines. By employing 2-hydroxyethylamines, the reaction can be extended to the preparation of 2-thiazolines via formation of β-hydroxythioamides.
