14311-78-5

Basic information

• Product Name: Silane, (4-methoxyphenyl)dimethylphenyl-
• CAS NO: 14311-78-5
• Molecular Formula: C15H18OSi
• Molecular Weight: 242.393
• Mol File: 14311-78-5.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Silane, (4-methoxyphenyl)dimethylphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (4-methoxyphenyl)dimethylphenyl-(14311-78-5)
• EPA Substance Registry System: Silane, (4-methoxyphenyl)dimethylphenyl-(14311-78-5)

Safety Data

• Hazardous Substances Data: 14311-78-5(Hazardous Substances Data)

Upstream product

• 100-66-3 methoxybenzene 
• 768-33-2 phenyldimethylsilyl chloride 
• 3517-99-5 1-methoxy-4-(methylsulfinyl)benzene 
• 1234935-78-4 (dimethyl(phenyl)silyl)zinc chloride 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 123-11-5 4-methoxy-benzaldehyde 
• 78646-39-6 2-(4-methoxyphenoxy)pyridine 
• 24588-72-5 2-(4-methoxyphenyl)-1,3-dithiane 
• 766-77-8 Dimethylphenylsilane 
• 17310-99-5 4-methoxy-N,N,N-trimethylbenzenaminium iodide 
• 696-62-8 para-iodoanisole 
• 459-60-9 1-fluoro-4-methoxybenzene 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 623-12-1 4-chloromethoxybenzene 

Relevant articles and documents

Hydride Transfer Enables the Nickel-Catalyzed ipso-Borylation and Silylation of Aldehydes

Nickel-catalyzed ipso-borylations and silylations of aldehydes are described for the first time. The new functional-group interconversion protocol is characterized by its scalability, functional-group tolerance and wide substrate scope, including examples of late-stage functionalization of complex molecules. The key for the successful reaction outcome is the use of a ketone as a hydride acceptor that intercepts the nickel hydride to undergo a reductive pathway, thus allowing formation of the desired C?B and C?Si bonds.

A nickel-catalyzed silylation reaction of alkyl aryl sulfoxides with silylzinc reagents

Ni(PEt3)Cl2-catalyzed silylation of alkyl aryl sulfoxides with silylzinc reagents was carried out. This protocol allows alkyl aryl sulfoxides to convert to arylsilicon compounds under mild reaction conditions, tolerates a range of functional groups and is suitable for a wide scope of substrates.

Nickel-Catalyzed Reaction of Aryl 2-Pyridyl Ethers with Silylzinc Chlorides: Silylation of Aryl 2-Pyridyl Ethers via Cleavage of the Carbon?Oxygen Bond

Ni-catalyzed C?O(Py) bond activation and silylation of aryl 2-pyridyl ethers with silylzinc chlorides were carried out. This protocol allowed the 2-pyridyloxy group to be substituted by a silyl group with short reaction times, mild reaction conditions, and good compatibility of functional groups. (Figure presented.).