143672-23-5

Basic information

• Product Name: cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III)
• CAS NO: 143672-23-5
• Molecular Weight: 596.268
• Mol File: 143672-23-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III)(CAS DataBase Reference)
• NIST Chemistry Reference: cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III)(143672-23-5)
• EPA Substance Registry System: cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III)(143672-23-5)

Safety Data

• Hazardous Substances Data: 143672-23-5(Hazardous Substances Data)

Upstream product

• 591-22-0 3,5-Lutidine 

Relevant articles and documents

Indium Complexes of 1,3-Diphenyltriazene

The reaction of InCl3 with 1,3-diphenyltriazene (Hdpt) in the presence of NEt3 gives the six-co-ordinate indium complex 1a.The interaction of 1a with Cl and Cl allows for the isolation of the appropriate salts, 1b and 1c.Reaction of Lewis bases, L, with 1a yields , L = pyridine 2, 3,5-dimethylpyridine 3, PEt3 4, L2 = 2,2'-bipyridine 5, 1,10-phenanthroline 6, Me2PCH2CH2PMe2 7 or Et2PCH2CH2PEt2 8.The mechanism for these reactions is discussed.No rection is observed between 1b and 3,5-dimethylpyridine.The X-ray structures of 1a, 3, 4 and 5 have been determined.Compounds 2-4 are readily soluble in aromatic hydrocarbon solvents, while 5-8 are insoluble as a consequence of the presence of a supramolecular architecture involving dipolar In-Cl---N interactions in the solid state.All new compounds have been characterised by 1H, 13C-1H> and 31P-1H> NMR and IR spectroscopy.